Volume 58, Issue 3

Abstract: In time the environmental conditions could damage textiles (materials/ artifacts) causing the need to develop better non-destructive or at least micro-destructive analysis techniques of the samples. There are ethnographic textile artifacts that were treated in the past with various pesticides, that have not been mentioned in any document. These are often re-treated with chemicals by museum staff as a method of preventing pest infestation. Due to the progressive use of many pesticides, this paper was focused on the detection and quantification of three pesticides: malathion, methoxychlor, and permethrin (cis- and trans- isomers). Gas chromatography is one of the most widely used analytical techniques for characterizing volatile organic compounds and therefore was the analytical method of choice for the present study. Because these analytes are found at trace levels, the detection and quantification limits of analytes are very small and it is necessary to optimize and validate a SIM method - that allows the mass spectrometer to detect specific compounds with high sensitivity. In SIM mode, the instrument is set to collect data at selected masses of interest, thus increasing the accuracy and precision of the quantitative results. The present paper is aimed to develop this type of method with specificity and selectivity, high precision (expressed in terms of repeatability and intermediate accuracy), accuracy, suitable working range and linearity, and high degree of series’ homogenity.

Abstract: The effect of mold conditions was investigated in terms of mold temperature (30oC and 90oC) and cooling time (30 s and 60 s) on the heat resistance of injection-molded bars for stereocomplex polylactide-b-polyethylene glycol-b-polylactide (scPLA-PEG-PLA). Comparative study was performed for poly(L-lactide) (PLLA) and PLLA-b-PEG-b-PLLA (PLLA-PEG-PLLA). scPLA-PEG-PLA was 90/10 (w/w) PLLA-PEG-PLLA/poly(D-lactide) blend. scPLA-PEG-PLA exhibited the easiest crystallization upon cooling scan as shown by differential scanning calorimetry (DSC). Higher mold-temperature and longer cooling-time induced higher degree of crystallinity as assessed by X-ray diffractometry (XRD) except for PLLA bars. The heat resistance of both PLLA-PEG-PLLA and scPLA-PEG-PLA bars was improved with increased mold-temperature and cooling-time as shown by dynamic mechanical analysis (DMA), vicat softening temperature (VST) and heat distortion-resistance tests except for PLLA bars. In conclusion, the heat resistance of injection-molded bars prepared at 90˚C mold temperature was in the order scPLA-PEG-PLA ] PLLA-PEG-PLLA ] PLLA. The results suggested that flexible PLLA-PEG-PLLA and scPLA-PEG-PLA with high degrees of crystallinity were successfully obtained by injection molding for use as good heat-resistant bioplastic products.

Abstract: The azo-chalcone dye of theophylline namely (E)-1-(4-((E)-(theophyllin-8-yl) diazenyl)phenyl-3-(4-dimethylaminophenyl)prop-2-en-1-one (TDPP) has been prepared and characterized by H-NMR, infrared, and electronic spectra, elemental analysis. Three solid complexes Mn(II), Ni(II) and Cu(II) of TDPP dye have been prepared and characterized by IR, electronic spectra, magnetic and conductivity measurements. The antibacterial and antifungal activities of the TDPP ligand and metal (II) complexes of Ni, and Cu are notable, with the copper(II) complex being more potent than the others. The TDPP ligand has interesting spectral properties as a pH sensor, solvent polarity sensor, and switches.

Abstract: Propargylamines are a promising but quite poorly studied category of organic compounds. This work aimed to study the photochemical properties of propargylamines polymers containing porphyrin fragments with electron transfer reactions. The study was carried out in 2019 at the Institute of Organic Chemistry (RAS, Moscow, Russia). The obtained polymer was irradiated with a luminous source. The absorption spectra were studied by electron paramagnetic resonance using a radio spectrometer. The presence of porphyrin and propargylamine in the polymer solution has been established to promote the reaction of complexation. This is due to the presence of double bonds in the amino groups, whereas also porphyrin and bromanil, which is an electron acceptor. The resulting data allow explaining the processes involved in photochemical reactions during the irradiation of the porphyrin complex in the presence of bromanil. In the long-wavelength part of the spectrum (above 540 nm), electron phototransfer inside the polymer molecule to the porphyrin side and between molecules from the porphyrin anion radical to the neutral polymer molecule take place.

Abstract: A series of methods were employed to assess the performances of advanced coating materials based on components that can modify the spectral parameters of the surfaces on which these materials are applied in order to obtain passive military camouflage. Powder materials with high infrared (IR) reflectance were used to obtain this type of coatings, which also ingrain in their structure a significant volume of air that allow limitation of the radiative heat transfer of the coated source. The components were embedded in a polyurethane matrix, which facilitated the coating process on different surfaces. The bicomponent polyurethane-based binder used within the different composition tested is transparent to incident IR radiation, has no organic solvents, is highly flexible and possesses remarkable physical, chemical and mechanical properties: high surface adhesion, high flexibility and resistance against a number of chemical agents and external factors with destructive effect. The efficiency of these composite materials was further demonstrated by analyzing the thermal images of different objects.

Abstract: This paper presents a characterization of PA6 and the blend PA6+EPDM (60/40) by tensile tests in order to evaluate several mechanical properties for impact resistance applications. Results were found to be dependend on test rate (10 mm/min, 250 mm/min and 1000 mm/mm). SEM investigation point out a homogenous structure. The blend has better value of energy at break, for the higher test speed: for v=250 mm/min this characteristic has the value of energy at break 29.7 J and the blend has 76.3 J. At 1000 mm/min, PA6 has this charcateristic of 20 J, but for the blend, it is almost insensitive for the two higher test speeds (76.3 J at 250 mm/min and 72.4 J at 1000 mm/min, respectively) as compared to the neat polymer that decreases this feature when thr test spee increases. At the lowest teste speed, the values of energy at break for the materials in this study are close (90.2 J for PA6 and 87.7 J for the blend). The results from tensile tests pointed out that the formulated blend is recommended for impact resistance applications.

Abstract: Recycling is a key process in any sustainable development strategy. This paper proposes solutions for the increasing waste collection rates by developing an educational model for developing innovative waste management solutions. The focus in this paper will be on making the correlation between experimental studies on compressive properties of recycling waste and designing a smart waste management compactor. Based on previous achievements on developing an innovative compactor system with selective waste collection, actual experimental trials will be analysed for generating compression patterns for different types of common waste containers which will be used in the conceptual design process of a compactor, impacting concept definition of all 3 subsystems: mechanical, electrical and software. A dedicated software module for compression parameters will be developed for importing experimental data trials and based on these to process and identify relevant compression parameters defining compression pattern for different common waste containers. These parameters will be used to assist the wok mode state machines for compacting wastes. This will improve compactor performance by optimization of compactor usage smart adaptability.

Abstract: This paper describes the mechanism and trend of High gloss polymer compounds replacing of paintable plastic parts in automobile industry, and gives some solution overcoming the appearance defects that Painting free parts form easily flow marks and Weld lines in injection molding.

Abstract: This paper presents a new basic nonlinear track model consisting of an infinite Euler-Bernoulli beam (rail) resting on continuous foundation with two elastic layers (rail pad and ballast bed) and intermediate inertial layer (sleepers). The two elastic layers have bilinear elastic characteristic obtained from the load-displacement characteristic of the rail pad and ballast. A time-varying load with two components - time-constant one and harmonic other, representing the wheel/rail contact force is considered as the track model input. Rail deflection due to the time-constant component of the load is obtained solving the nonlinear equations of the balance position. Subsequently, the structure of the nonhomogeneous foundation is determined. Dynamic rail response in terms of receptance due to the harmonic component of the load is calculated using the linearised track model with nonhomogeneous elastic characteristic. Influence of the time-constant component and the reflected waves due to the nonhomogeneous foundation are presented.

Abstract: The main objective was to reduce the consumption of material when obtaining 3D printed parts (different empty shapes inside) and the secondary one was to maintain the mechanical properties closer to the full printed version. In order to achieve these objectives, two internal configurations were designed - a configuration with hexagonal gaps (material reduction was 30%) and a configuration with sinuous gaps (material reduction was 15%). The specimens thus obtained were tested for traction, three-point bending and shock (resilience). Hexagonal hollow configuration has a resistance values close to those of solid specimens but with the advantage of consuming with 30% less material.

Abstract: Polymethyl methacrylate (PMMA) is one of the common widely accepted biomaterials in prosthetic dentistry due to its acceptable advantages, since 1937. In the present work, PMMA reinforced with Al2O3 nanowires (Al2O3 NWs) and ZrO2 nanoparticles (ZrO2 NPs) were fabricated by a self-curing method. Mechanical and tribological tests were conducted to study the effect of nanofillers on the mechanical and tribological performance of PMMA nanocomposites. Compression and microhardness tests, as mechanical tests, were accomplished to estimate the elastic modulus and microhardness number of the present nanocomposites. Also, tribological properties of unfilled PMMA and its nanocomposites were realized by pin-on-disk tester under dry sliding conditions. Wear test was conducted at room temperature under applied loads of 10, 20, 30, 40, and 50 N at a constant sliding speed and distance of 1.256 m/s and 226 m, respectively to study wear rate and coefficient of friction (COF) of the nanocomposites. Experimental results revealed that the elastic modulus, microhardness, wear rate, and COF were enhanced with increasing nanofiller content up to 0.5 and 0.7 wt. % of Al2O3 NWs and ZrO2 NPs, respectively. Also, wear rate increased with increasing applied loads up to 50 N, while COF decreased with increasing applied loads up to 40 N. Finally, specimens’ worn surfaces were examined and imaged using scanning electron microscope (SEM).

Abstract: This study presents a Solidworks® Plastics application in a company in the Automotive Industry for the aftermarket of auto parts manufactured by the injection molding process, the focus is on the redesign of an injection vein plate for achieve uniform filling of a 16 cavity mold with a geometry made up of a mixture of natural rubber and two metal components. This work proves that the use of symmetrical commands is not always the best option. The distances between runners were not taken into account as a source of the future wears problems in the mold. A layout is created with a combination of 2D and 3D sketches by turning the injection chanels 180° in the problem cavities to increase the distances between runners and the filling of the 16 cavities is verified by simulation. It is also demonstrated by simulation that increasing the injection point size is not necessarily always the best option for cavity filling.

Abstract: The recycling of high-density polyethylene plastic (HDPE) plays a crucial role in sustainable development. However, obstacles to the use of recycled HDPE remain because of the material and processing properties and odors of recycled HDPE. The odor of recycled detergent bottle plastic leads to rejection by most detergent manufacturers. Recently, some recycling enterprises have adapted recycling with odor reduction processes involving the use of solvents, antimicrobial additives, and odor extraction units in feeders and extruders. However, these processes may affect the quality and cost of recycled plastic. Most small and medium businesses (SMBs) may not favor these effects due to their limited models and resources. In addition, most SMBs are unwilling to replace their current recycling operation units. Hence, this study aimed to find alternative and economical ways for odor reduction in the recycling process. A modification of the recycling process was introduced in the pretreatment of plastic flakes before entry into the feeder of an extrusion unit. The effect of selected washing temperatures, i.e., 65℃, 75℃, 85℃, and 95℃, on the removal of odor from recycled HDPE was further studied. The addition of sodium bicarbonate, calcium carbonate, and citric acid into a heated water bath enhanced the deodorizing effect. The relationship of these three chemicals with the deodorization of HDPE plastics was investigated through sensory evaluation. Lastly, the potential of the deodorized recycled HDPE for resin pellet production and commercialization were investigated.

Abstract: The investigation on the effect of adding silane modified chopped E-glass fibre and Aluminium metal wire-mesh into nano silica toughened nylon 6-6 thermoplastic composites on mechanical, drop load impact, fatigue and tribological behaviour is studied in this paper. The primary aim of this research work is to develop a hybrid Nylon 6-6 nanocomposites having high stiffness, toughness and wear resistance. The chopped glass fibre and Al wire-mesh was surface treated with the help of 3-Aminopropyletrimethoxylane (silane) and acid etching. The tensile results revealed that additions of glass fibre and Al mesh into nano - silica toughened nylon 6-6 composite gives improved tensile and flexural strength. Similarly, the Izod impact strength of Al-mesh reinforced nano silica (1vol.%) toughened nylon 6-6 gives superior energy absorption up to 6 Joules/cm. The drop load impact penetration of composite N3 (59% - Nylon 66, 20% - E-glass fibre, 20% - Al wire mesh and 1 % - nano silica) shows very limited penetration than other composites. Highest fatigue life of 16391 cycles was observed for the composite designated N3, which contains 1 vol.% of nano silica, whereas the composite containing 2 vol.% of nano silica gives very lower specific wear rate and Co-efficient of friction. The developed composite which has better modulus, stiffness, wear resistance and fatigue life could be possibly used in automobile power transmission gears, domestic equipment and farm related machineries.

Abstract: Great interest has been shown lately in bio-composite materials because they are inexpensive and sustainable. Composites with matrices and natural reinforcers have been little studied. Here, we study certain mechanical properties of composite materials with a Dammar-based matrix (also named hybrid matrix) and flax fabric reinforcement. To be precise, we examine three types of resins where Dammar is the major component, with a volume proportion of 55%, 65% and 75%. In this respect, we have made composite materials reinforced by two types of flax fabric and we have measured the characteristic curves and some mechanical properties, such as the Young’s modulus, tensile strength and elongation at break using tensile tests. Based on the obtained properties, it is proposed or possible to use these materials in orthopedics.

Abstract: News on Green Energy and Green Hydrogen is spread on popular and academic media. When energy is obtained from sunlight, wind or water, we call it Green Energy. When hydrogen is obtained from electrolysis with Green Energy, we call it Green Hydrogen. Hydrogen Fuel Cells are electrochemical devices that convert hydrogen and oxygen`s chemical energy into electricity and heat energy with high efficiency and contribute to the decarbonisation of the power supply. Bipolar plates, essential components of the fuel cells, made in polymer-carbon composites, are an economical alternative to the stainless steel, titan and graphite, traditional materials. Our experiments have used a polypropylene matrix filled with graphite with a total inorganic content of 87%, which contributes to high electrical and thermic conductivity but strongly influences the viscosity, flow, pressures, temperatures, and then challenging to process. Injection Moulding of thermoplastics is a technology widespread in all fields of activities and considerable potential. In this paper, the experiments` design is highlighted in choosing the factors. A debate regarding the filling, packing, holding pressures, and the last decades` approach and optimisation of injection moulding parameters with the Taguchi Method is presented. Conclusions on the injection moulding process of the bipolar plate made of a polypropylene-graphite composite, the parameters` influence with direct effects on the fuel stack`s performance are presented. The combined melt and mould temperatures influence most electrical conductivity by better contacting the electrically conductive particles through the polymer`s melted layer. The injection pressure influences the mass and thickness of the product and the electrical conductivity by better packing. Furthermore, we suggest an adapted formula to predict the injection pressure considering the inorganic content and the process temperatures in agreement with the experiments.

Abstract: In this study, the properties of unsaturated polyester resin were studied in the presence of recycled ceramic waste particles. Herein, composites were created that contained 28.5-50 wt% porcelain particles (particle size [180 µm). High filler contents increased the gel time and decreased the exotherm temperature of unsaturated polyester resin during curing. The obtained results showed that physical parameters, such as the resin density and porosity, increased as the filler content increased. In addition, the X-ray diffraction results indicated that the produced samples were a combination of ceramic waste particles and unsaturated polyester resin, resulting in semi crystalline structure. The results showed that the maximum water absorption at 40°C increased from 0.97 to 1.5% as the filler content increased from 28.5 to 50 wt%; in this process, the materials experienced a color change but did not lose mechanical performance. Finally, the samples were characterized by thermogravimetric analysis (TGA) to study the effect of porcelain powder on the thermal degradation of the resin. The TGA scans were analyzed with the Friedman method. The results indicated that the samples with porcelain powder exhibited substantially better thermal stability than unsaturated polyester resin.

Abstract: Samples of LDPE (low-density polyethylene) and LDPE-PANSA (low-density polyethylene -4-Amino-3-hydroxy- 1-naphthalenesulfonic acid) copolymer with Ag0.5·Ni0.5·Fe2O4 powder (as a filler) composites were developed. Following the preliminary characterizations on the thermooxidability (by thermal analysis techniques), the dielectric behavior (by dielectric spectroscopy technique), the mechanical behavior, etc. it was found that the developed materials do not show significant changes after 240 h exposure to 150 mW / m2 UV. The addition of 3wt% PANSA in LDPE has the effect of increasing the mechanical performance of polymer composites with Ag0.5·Ni0.5·Fe2O4 filler. The addition of 15 wt% ferritic powder leads to significant increases in dielectric losses (by about 100% in the case of pure LDPE and about 185% of the LDPE copolymer with 3 wt% PANSA) and to the increase of the real component of the relative permittivity (by about 34.4 % in LPDE, respectively about 36.4% in LPDE copolymer / 3% wt PANSA). Dielectric behavior of the investigated materials indicates that the effect of Ag0.5·Ni0.5·Fe2O4 powder in LDPE and of copolimer LDPE with 3 wt% PANSA consists in the increasing of the shielding efficiency of electromagnetic waves - the maximum effect being recorded in the case of the composite material with the content: LDPE 84.5 wt%, 2.5 wt% / PANSA and 13% wt% Ag0.5·Ni0.5·Fe2O4.

Abstract: Initially developed as a rapid prototyping tool for project visualization and validation, the recent development of additive manufacturing (AM) technologies has led to the transition from rapid prototyping to rapid manufacturing. As a consequence, increased attention has to be paid to the mechanical, chemical and physical properties of the printed materials. In mechanical engineering, the widespread use of AM technologies requires the optimization of process parameters and material properties in order to obtain components with high, repeatable and time-stable mechanical properties. One of the main problems in this regard is the anisotropic behavior of components made by additive manufacturing, determined by the type of material, the 3D printing technology, the process parameters and the position of the components in the printing space. In this paper the influence of the printing orientation angle on the tensile behavior of specimens made by material jetting is investigated. The aim was to determine if the positioning of components at different angles relative to the X-axis of the printer (and implicitly in relation to the multijet printing head) contributes to anisotropic behavior. The material used was a photopolymer with a mechanical strength between 40 MPa and 55 MPa, according to the producer. Four sets of tensile test specimens were manufactured, using flat build orientation and positioned on the printing table at angles of 0˚, 30˚, 60˚ and 90˚ to the X-axis of the printer. Comparative analysis of the mechanical behavior was carried out by tensile tests and microscopic investigations of the tensile test specimens fracture surfaces.

Abstract: Graphene, a two-dimensional crystalline allotrope of carbon, has received greater attention from numerous researchers due to its excellent properties. Graphene could be produced by various techniques, each method has its advantages and disadvantages. In this research article, a novel method using agricultural waste rice husk as a precursor and chemical activation to produce few-layer graphene nanosheets was developed. Traditional approaches` significant shortcomings and the environmental concern of agricultural waste have been eliminated. The synthesized material was characterized using FESEM, Raman Spectroscopy, X-Ray diffractometer, UV-Vis absorbance and FTIR analysis. FESEM analysis of the surface morphology revealed smooth edge few-layer graphene. The formation of sp2 hybridized atoms can be seen in XRD spectra at 26.3 degrees. The C=C stretching bonds detected at 1612 cm-1 wavelength are responsible for the graphitic structure.

Abstract: Some inventions along with theoretical and experimental research made it possible to increase the output of a thermally homogeneous melt provided by the screw. However, the quality of the extruded product depends on some specific features of the extrusion die and to a large extent on the rheological behavior (viscous and elastic) of the polymer melt. The mismatch between the design of the screw-cylinder subassembly and the design of the extrusion die results in products with relatively short service life. The present paper has drawn up the working field of the extruder die and adjusted it based on the limitations imposed by the screw-cylinder subassembly, namely: - the maximum output rate that ensures the required thermal homogeneity of the melt; - the maximum output at which the heating system on the barrel (and possibly the screw) ensures the extrusion temperature; - the minimum economic output corresponding to the diameter of the screw. The working field of some extrusion dies for blown films of the following polymers have been plotted: polypropylene, low density polyethylene, high density polyethylene and ethylene vinyl acetate.

Abstract: The number of surgical procedures for abdominal wall defects is increasing, often requiring the insertion of plastic material meshes. Surveillance of patients with inserted plastic meshes requires an accurate determination of the position of the mesh. However, this is a difficult task, depending on the kind of mesh, magnetic resonance imaging (MRI) protocol or consistence of the surrounding tissue (fat, muscle, aponeurosis). The aim of our research was to develop an experimental model to test the ability of MRI to identify the exact position of surgical plastic meshes: polypropylene or polyester. To simulate the placement of a mesh in human body we developed a model built up from two pieces of tissue with dimensions of 40 cm x 20 cm, harvested from a pig with a weight of 120 kg. The meshes were situated for MRI evaluation between the two pieces: abdominal pig muscle respectively suprajacent abdominal pig wall subcutaneous fat, approximately 2 cm high. Five surgical meshes were scanned through six MRI sequences, in view of establishing an optimal MRI scanning protocol and best visible meshes. The MRI scans were evaluated by 5 radiologists with different degrees of training. Our results showed that the experimental model developed by us can be successfully used to test the ability of MRI to visualize different kind of plastic meshes. Also, our experiment has revealed that T1fl2D sequence is the best in highlighting meshes from surrounding tissue, and the best visualized Mesh was number 4, made of polyester. In conclusion, based on our experimental model, we should select a plastic mesh or MRI protocol which will allow an optimal post implantation monitoring. Modern technology of material’s fabrication can help to better identify the mesh itself using MRI scanning.

Abstract: This study determined and compared the influences of various processing techniques including air circulating oven (ACO), dry heat oven (DHO) and water bath (WB) on the impact strength (IS) and microhardness (HV) of the conventional heat cure acrylic resin (CHCAR) and rubber reinforced heat cure acrylic resin (RRHCAR). Samples were fabricated using CHCAR (control Group A; n=114) and RRHCAR (experimental Group B; n=114). Group A and B were further divided into subgroups according to processing techniques: ACO, DHO and WB (n=38 each) for both testing variables microhardness and impact strength (n=19 each). Charpy testing machine and Vickers microhardness tester were utilized. Analysis of variance was applied to determine the presence of significant differences among processing techniques while P-value ≤ 0.05 was considered as significant. Water bath (P-value [0.001) and DHO technique (p-value [0.001) showed significant differences between both groups’ impact strength and microhardness. Microhardness of group A and B showed a significant difference (p-value 0.002) when processed by ACO. Impact strength and micro hardness were improved in RRHCAR compared to CHCAR processed by ACO and DHO in comparison to WB technique. Rubber reinforced heat cure acrylic resin revealed improvement in the impact strength and microhardness. The air circulating oven exhibited highest microhardness in both testing materials. Dry heat oven showed improved values of impact strength in conventional heat cure acrylic resin.

Abstract: Mechanical characterization of newly developed polymers and composites are the basic measurements that are used to check the potential of the material towards its usage in various applications. Young researchers who are new to the field of materials science often find it difficult in selecting the specific testing standards for their novel materials. This review article provides a detailed explanatory of the various ASTM standards that are used for analyzing the basic mechanical properties of polymer composite materials. The standard dimensions of the test specimens and the mechanical testing parameters that are universally followed in different testing phases are illustrated for the ease of research.