Cavitation Erosion Behavior on Thin Films of Polymer Blends Deposited Over Bronze Surfaces
The composite materials with polymeric matrix represent a great realization of chemical engineering. Their applications in all the industrial fields are dictated by their chemical, physical and mechanical properties. In the last 50 years the polymeric composite materials received a large use in the protection and repair work of the surfaces in contact with fluid currents of various natures. The scientific researches followed by the industrial use, show that the polymere films with certain composition and properties have an excellent behavior to chemical, abrasive and cavitation erosions. Because the most stressed machine details subjected to cavitation erosions are the blades, runners and impellers of hydraulic machines as well as the ship propellers, researchers are looking for the best polymers to increase the running time, or for the use in covering the zones with shallow erosions, during the repair work. In this direction is oriented also the present research, performed in the Cavitation Laboratory of the Timisoara Polytechnic University. The obtained cavitation erosion for specimens covered with different polymere films is compared with those realized in identical conditions, but for specimens without protection films. The results show that the films assure some increase in the resistance to cavitation erosion but the tested polymer layers have reduced adherence on the metal surface.
The Antioxidant Effect of PLGA Nanoparticles Encapsulated with Lutein in Rats Treated with Hypercaloric Diet
Poly lactic-co-glycolic acid (PLGA) is a biodegradable polymer that has been the focus of intense research due to its potential applications in medical research. Its uses in nanotechnology are underlined by its capability of targeting various cells and delivering active compounds to different human tissues. To date, PLGA nanoparticles are employed in areas such as vaccination therapy, diagnostic imaging procedure and various applications in various anticancer therapies. The aim of the present study is to measure and evaluate different correlations between oxidative stress parameters in spleen and liver following administration of nanoparticles encapsulated with lutein in an animal model. Our results show that acute oral administration of PLGA NPs induces a change in the oxidative stress status in both liver and spleen of rats, but does not induce oxidative stress damage to cell structures such as lipids or proteins.
Bending and Compressive Analysis of Epoxy Resins Modified with Low-polar Solvent Solution of Polysulphone
The memory shape materials seem to be extremely promising materials for medical applications especially as inserts to support the muscular system. In the case of memory shape polymers a supplementary issue is related to their bio-compatibility such as they can be rejected by the organism even their properties are fitting the requirements. Present study started from the hypothesis that mixing the epoxy resin with other polymers some valuable materials could be obtained especially for energy storage. The epoxy resins possess extraordinary properties (relatively to other thermoset polymers) but they also show an excellent stability that generates problems when this type of materials should be neutralized. Epoxy resins also show low water or other liquids absorption due to their low porosity and they cannot be used for energy storage applications when mobility of charge carriers is ensured by liquid phase. A polymer with high porosity used for membrane formation is the polysulfone and, in this regard, tests were performed to analyse the ways to mix an epoxy resin with polysulfone. The idea had generated a study regarding the properties of such a mixture together with the condition that had to be reached to successfully get the mixture. Low-polar solvent solution of polysulfone had been obtained with 1-methyl-2-pyrrolidinone. After compatibility tests, 15 and 20% of this solution was added to the components of the epoxy systems -with the epoxy resin -and formed materials were analysed by mechanical means-compressive and three-point bending - the surprise was that some materials had showed memory shape properties.
Evaluation of AML-VAL Nanoparticles as Combined Therapy in Cardiovascular Disease
The main aim of this study was to investigate a mixture of two poorly water-soluble active pharmaceutical ingredients (APIs): an angiotensin II receptor antagonist (valsartan) and a calcium channel blocker (amlodipine besylate), chosen in a fixed-dose, in order to obtain new polymeric nanoparticles (NPs) for cardiovascular diseases treatment. NPs were prepared via nanoprecipitation method using poly (D,L-lactide-co-glycolide) (PLGA) as matrix and Pluronic F127 as stabilizer. Three formulations were investigated with different ratios of AML:VAL:PLGA (1:16:5, 1:16:7.5 and 1:16:10). Particle size, polydispersity index and zeta-potential analyses were performed to characterize and optimize the formulation. The in vitro drug release study was determined by using a dialysis membrane method under sink conditions. All NPs loaded with both APIs showed nano-size, negative potential, a high homogeneity and a slow drugs release in physiological environment.
A Step Forward Standardization of Biocompatibility Testing on Tissue Culture Polystyrene
Standard procedures regarding osteoblast cells deposition on different subtrates to test the biocompatibility of materials are not available. Aspects related to cells morphology depending on their number on the surface area of the substrate were studied for the first time. Osteoblasts were successfully isolated from residual bone resulted from two different patients after total hip arthroplasty. Different numbers of osteoblasts in populations (3x104 cells/cm2, 6x104 cells/cm2, 1x105 cells/cm2) were deposited on tissue culture polystyrene for 7 and 10 days of incubation. Results suggested that the protocol of osteoblasts deposition should be adjusted to assure a fair distribution of cells on the entire available area of the substrate, possible if a very good dispersion in the medium is achieved prior to deposition. Some other key factors in cells appropriate development, such as substrate nature, topography and incubation time,were detected. The present investigation helps declaring specific standards with respect to the biocompatibility testing of materials using osteoblast populations. Further investigations may lead to the creation of databases and the establishment of standards regarding bicompatibility researches that involve osteoblasts populations.
Simulation of Mechanical Behaviour in Milling and Polishing of Dental Polymeric (resin) Composites
Dental resin composites have a wide applicability in the dental field. They exhibit their own chemical composition that imparts certain physico-mechanical properties. The machining of the pieces of these composites must be sufficiently light, without affecting their strength. For processing these parts, respectively of the dental work, is used or carbide burs, or diamond burs, depending on the mechanical strength of the composite. To determine composite behaviour under action of the conical finishers was simulated their behaviour in specific simulation programs. As a result, stress concentrators may appear from the first processing which may affect the later resistance of the piece or dental work.
Synthesis and Mechanical Properties of Polyurea-Based Hybrid Composites for Ballistic Individual Protection
During conûict situations, the combat staff is exposed to a wide variety of aggressions, such as temperature and pressure variations and dynamic impacts (from ammunition or fragments). Textiles used in the manufacture of the military uniforms and devices have always played an important role in defending the military against these hazards, and an adequate level of individual protection equipment is required. In this respect, novel fibre-reinforced polymer composite materials for military application, such as reducing blunt trauma for ballistic protection equipment, have been studied in terms of thermal and mechanical properties and ballistic protection, obtaining very good results.
Assessment of Paint Layers Quality 1. Field investigations on a railway bridge
By electrical determinations, digital microscopy and visual observations, the anticorrosive insulation capacity of the paint layers applied to the three sections of a bridge over the Tisza River was assessed. The visual observations have highlighted the fact that on the Eastern section repainted in 2013, biofouling increases are significant (covers up to 10 % of the surface) - both ferns have been identified (Hypogymnia physodes and Xanthoria parietina), filamentous molds (Aspergillus fumigatus and Aspergillus niger) as well as algae and moss (green - capable of photosynthesis). On paint applied in 1986, no bio fouling was visible but the painting material is aged and shows rust traces (5-10 % of the surface) and exfoliation between the paint layers (10-20 % of the surface). No bio fouling and/ or exfoliation/ degradation of the paint layer have been observed on the paint applied in 2014. Determinations of electrical insulation resistance correlated with those of the paint layers’ thickness are closely related to the visual observations. The values obtained for the specific resistivity of the paint layers applied in 2013 (with bio fouling increases) are approx. 38 times lower than those applied in 2014. These findings suggest that the painting material used in 1983 for the top coat realization, showed major qualitative vices.
The Most Significant Influences of Decontamination Mixtures Containing Chlorinating and Oxidizing Agents on Barrier Materials Formed by Isobutylene-Isoprene Rubber
The influences of hypochlorite DM with oil ingredient and without it, which is introduced into the armament not only by the Czech Armed Forces Chemical Corps, but also by the chemical services specialists of the Czech Republic Fire Rescue Service, on a substrate consisting of a barrier material based on isobutylene-isoprene rubber (butyl rubber) were presented in this paper. Based on the repeated exposure of the substrate formed by the barrier layer material selected by this decontamination mixture and its subsequent rinsing, a change of the breakthrough time has been studied using the MIKROTEST method employing the chemical warfare agent of sulfur mustard and Congo red as a detecting agent.
A Brief Presentation of the Characteristics of Hemodialysis Membranes
The survival of CKD patients has known significant improvement with the appearance of extrarenal clearance methods. Being a domain in a rapid progression, the hemodialysis membranes have been, in time, one of the key modifying points. In this paper will make a short presentation of the features of hemodialysis membranes and will point out aspects which need future research.