With technology becoming more and more advanced, the medical system is being consistently improved. From intraoral scanners that started to replace conventionally impressions technique to printed surgical guides that directs the drilling systems of implants, dentistry is one of the beneficiars of new and advanced treatments that are ergonomic, safe and put both the medical team and the patient in a more pleasant experience. The purpose of our article is to summarize the application of acrylic and metacrylic resin in 3D printing of surgical guides used in orthodontics.
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Thermoplastic polymers have found widespread applicability in electronic industry owing to their facile processing and relatively low costs. Transparent polymer foils, like polyethylene terephthalate (PET), can be utilized in manufacturing components for liquid crystal display (LCD) devices. This work is focused on surface processing of PET through different procedures. The induced surface modifications of polymer samples were analyzed by optical microscopy. Contact angles of nematic drops on PET film are measured to evaluate how the method of surface modification reveals that the surface texturing affects the interactions of polymer with the liquid crystal. The influence of created surface anisotropy on the work of adhesion at polymer/liquid crystal interface is analyzed. Preliminary assessment of nematic orientation on the surface of modified PET foils is performed using polarized light. The results were discussed in regard with the used methodology to adapt the surface of the PET films to achieve optimal orientation of nematic molecules. The obtained data will open new perspectives on processing polymer foils as alignment layers used in LCD devices.
Abstract.The paper aims to present research on the determination of the coefficient of acoustic absorption as a function of frequency, for composite monolayer plates (made of: MDF - wooden dried agglomerated fibres with medium density, RWB – rebated wood from dried beech, PS - extruded polystyrene) and multilayer (with outer coatings of: MDF, RWB and polymeric core of extruded polystyrene). The sound-absorbing behavior of such plates is highlighted in the cabins made of multilayer structures.
In this study, a new solution for the development of an antiradar camouflage by overlaying several mono-pigment polymeric structures in a composite structure is provided. In this respect, powder materials with antiradar properties (carbon nanotubes, graphite, active charcoal, aluminum trioxide) were embedded in polymeric matrices. The performances of the developed products were tested using an experimental device for the measurement of electromagnetic efficiency within the frequency range from 1 to 18 GHz.
Lately, PP-R pipes have become increasingly popular in terms of drinking water installations and heating. Comparated to the classic pipes from copper or steel, pipes from propylene are much easier to use, they have obvious qualities and they are marketed at a much lower price. The study aims a comparative analysis of the physical-mechanical properties of the four most common types of pipes from propylene, which are currently found in commerce : simple without insertion(PP-R), with insert of composite fiber (PP-R-CF), with insert of basalt fiber (PP-R-BF) and with insert of aluminium (PP-R-AIF). Experimental research showed that from the point of view of thermal expansion, the best behavior is from the pipes from propylene without any insert and the value of the thermal expansion coefficient for the reinforcement pipe with basaltic fiber is very small. After these attempts at tensile, it resulted that all four samples which were analyzed from the point of view of the tensile strength, don’t exceed the limit that was given by the manufacturer (10-30 MPa), the values obtained being: for pipe from polypropylene of 17 MPa, for pipe from polypropylene with insert of aluminium of 18 MPa, for the test tube from pipe of polypropylene with insert of basalt fiber of 29 MPa and for the test tube from pipe of polypropylene with insert of composite fiber of 30 MPa. Therefore, from the point of view of the behavior at tensile and bending, the best behavior is from the pipes from polypropylene with insert of basalt fiber and pipes from polypropylene with insert of composite fiber.
Background. The macroporous polyurethane ether foam was introduced in the medical field, as early as the 90 ties, for the Vacuum-assisted closure (V.A.C.) of a wound. We describe our experience after treating abdominal wound dehiscence in a group of elderly gynecological patients with NPWT (Negative Pressure Wound Therapy), using ether foam coated with a silver layer. We reviewed elderly patients chart data that underwent abdominal surgery complicated with wound dehiscence treated with VAC for eighteen months. In all patients, the system used was the standard GranuFoam Silver™ dressing (different extents), which was usually replaced every 48/72 h. A total of 15 consecutive female patients were included. The median age was 67.3 (58-71) years. Duration of VAC treatment was median 14.2 (11-34) days, and we saw an improvement in wound repair but also clearance of S.S.I. on the third day after applying V.A.C. Ulta™. Definitive secondary closure of the wound was obtained in all patients, as the infection’s site clearance. The abdominal VAC treatment with GranuFoam Silver™ dressing in patients with infected abdominal wound dehiscence is safe and has proper patient compliance. The latest evolution of the silver foam polyether dressing, in conjunction with NPWT therapy, offers a better antimicrobial effect and shorter healing stage.
Diabetes mellitus (DM) and cardiovascular diseases (CVD) represent worldwide, major health problems. Frequently, diabetic patients may require therapy with implantable intra-cardiac electronic devices. In this article, we analysed the complications related to the presence of polymer-coated electrodes leads occurred among 351 patients, carriers of implantable electronic intra-cardiac devices: permanent pacemakers (PPM), cardiac resynchronisation therapy (CRT) or implantable cardioverter-defibrillators (ICD). Of all these patients, 99 (28.20%) had type 2 DM (p=0.022), double than the prevalence of DM in the general population (11%). Only two patients with PPM and DM had fractures of electrodes leads and one was diagnosed with right heart infective endocarditis, but no non-diabetic patient developed any complications related to the presence of polymer coated electrodes leads.
The paper presents the manufacturing process of advanced composite wind turbine blades designed for an experimental counter rotating vertical wind turbine (CR-VAWT). An iterative approach was used to present the manufacturing process of turbine blades starting from presentation of the turbine structure and material description as well as all manufacturing process stages. Two types of turbine blades were successfully manufactured using metallic molds and a cost-effective manufacturing technology. Based on the turbine blades obtained it can be said that the selected manufacturing process showed good results, very similar with results expected in case of using advanced technologies (i.e. autoclave technology.
The aim of this in vitro study was to evaluate the characteristics of four commercial dental composites: two dual-curing luting resin cements and two indirect composites for crowns and bridges. The novelty of the study consists in the use of combined characterization methods for the investigated materials, namely: after maintaining the samples in the water/ artificial saliva, besides sorption, the surface degradation of the samples was observed after their immersion period; thereafter, the immersion medium was lyophilized and then the percentage of residual monomer found in the medium was determined by HPLC. After 44 days, small concentrations of monomers have been determined in the aqueous/saliva extracts. SEM images show that the samples from each class of material, with a higher content of inorganic filler, exhibit a larger erosion of the surfaces after contact with water compared to the other two samples that show a larger erosion of surfaces after contact with saliva than with water. The surface of the dual-curing resin cement with a higher content of inorganic filler is the smoothest from the samples exposed to saliva, instead the other resin cement is the roughest, as shown by AFM analysis. The overall observation reveals that the samples kept in saliva are rougher than the ones kept in water. Smooth surface materials of both classes of materials ( with a higher content of inorganic filler) have absorbed a higher amount of water / saliva compared to materials with a rougher surface.Water sorption in the composite resins is influenced by the hydrophilicity of the monomers, the nature and size of the inorganic filler particles, and the quality of the matrix / filler interface.
The main objective of the paper was to prepare eco-friendly chiral hydrogels from chitosan and betulinic aldehyde under ultrasonic radiation effect, targeting their use for enantiomeric separations. This strategy promoted the obtaining of the hydrogels by supramoleclar organization of the imine units bonding the betuline skeleton with chitosan into ordered clusteres, while not altering the physico-chemical properties of the reagents. FTIR, SEM, CD spectroscopy and POM techniques were used to prove the pelicularities of the hydrogelation mechanism under the ultrasonication. The stability of the hydrogels was investigated by monitoring the influence of the swelling in three media of diferent pH, by POM and CD. It was concluded that the chiral hydrogels prepared by ultrasonication are stable when the pH vary from acidic to basic, indicating the new synthetic approach as a valuable method to yield suitable materials for enatiomeric separations in medical field.