A Theoretical Model for the True Hardness Determination of Ni-P / SiC Electroplated Composites
In this work we have applied a Hays –Kendall mathematical model to the Vickers microhardness values to eliminate the troublesome indentation size effect (load dependence of hardness) and obtain a unique value representing the true hardness for each coating. Examination of the unique hardness values has been possible in conditions of heat treatment at 190 0C and 420 0C. Key words: Hays –Kendall model, Ni-P/SiC coatings, hardness, ISE effect, heat treatment
HEMA Based Copolimers as Future Materials in Intervertebral Disc Replacements
Degenerative disc disease in the lumbar spine is marked by a dehydration of the intervertebral disc and loss of biomechanical function of the spinal unit. Since the current surgical procedures are ineffective in restoring natural biomechanical function back to the diseased disc, researchers have looked to replace the intervertebral disc. These designs are flawed in that they either don’t restore natural movement back to the spinal unit, require surgeries that are highly invasive, or they further promote disc degeneration of adjacent spinal levels. Recently, researchers have sought to only replace the central portion of the disc called the nucleus pulpous. A potential nucleus replacement could mimic a healthy nucleus pulpous in restoring healthy biomechanical function to the spinal unit. A hydrogel, poly (vinyl alcohol) (PVA), has been investigated to serve as a nucleus replacement. However, semi crystalline PVA suffers dissolution under physiological conditions and for this reasons are tested others hydrogels (HEMA) which are biocompatible, maintain the liquid transport function, the shape and the size of intervertebral disc and are very good shock-absorbent. Keywords: prosthesis, hydrogel, HEMA, intervertebral disc
Order Degree of Polyvinyl Alcohol (PVA) Films, Estimated by a Spectral Method
Poly-(vinyl alcohol) (PVA) films, colored with pyridinium ylids and dried by water evaporation, become stretched under the heating influence. The visible electronic spectra of the stretched films were measured for linearly polarized visible radiations having their electric field intensity parallel and perpendicular on the stretching direction. The dichroism of the colored PVA films depends on the stretching degree. The birefringence of each film was estimated by using a polarizing microscope with compensatory wedge. Keywords: stretched PVA films, pyridinium ylids, dichroism, birefringence
The Heat Transport in Nanofluids: a Theoretical Approach Through the Fractal Theories
A mathematical model of the heat transport in nanofluids using the fractal theories (the scale relativity theory in the topological dimension DT = 2) is established. Through a scale covariance form of the Newton’s equation, a Navier-Stokes type equation with an imaginary viscosity coefficient and particularly a Schrödinger’s type equation are obtained. Some applications of the model are given like the heat transport through an effective thermal conductivity, by Brownian motion or by liquid layering at liquid-nanoparticle interface. It results that the heat transport in nanofluids is performed through an unique mechanism, the above standard sequences mentioned being imposed by the interaction scales. Moreover, the quantum thermal conductance of electrons in an one-dimensional wire is obtained. Keywords: nanofluid, heat transfer, fractal, thermal conductance
On the Behaviour of Elastic Elements Belonging to the Elastic Tram Wheel at Particular Loading
The paper proposes an analysis on the influence of the elastic rubber elements as component parts of the elastic tram wheels, as well of the railroad, on the stress state, on the wear and the loss in time of the mechanical properties under dynamic conditions. It is noticed the importance of the proping of the rubber elastic element (all degrees of freedom or vulcanized on a metallic support) going to a „brick” element shape proposal, which is absolutely „covered” for practical applications. This approximation leads to new correction coefficients, as well as to the validation of the simplified „brick” shape of specimens for a future experimental test standartization. Keywords: elastic wheel, stress, mechanical testing, finite element analysis
Polyolefines Mechanical Recycling Considering the Carbonyl Variation During the First Life (II)
A degradation mathematical model based on the dependence of the carbonyl index by the degradation time to measure the polyolefins degradability was proposed. The mathematical model was verified with good results with own and literature degradation data. It was demonstrated that the three aging parameters of the mathematical model that can be calculated by fitted method, reflect the degradation behaviour of primary and secondary polyolefins and can be used for quantitative estimation of the polyolefins degradability. The possibility of using the mathematical model for estimation the opportunity of using the mechanical recycling as recycling method is the practical importance of the obtained results. There is also, a mathematical demonstration of the reason for which the polymers can not be infinitely recycled as other materials like metals, glass e.g. Keywords: mechanical recycling, ageing parameters, contamination
Variation of Friction Factor Through the Gait Cycle in an UHMWPE-CoCrMo Hip Endoprosthesis
The frictional factor of new hip endoprosthesis was measured using one hip testing device designed in Biomechanics Laboratory of Medical Bioengineering Faculty. Hip simulator respect physiological condition (variable load, variable motion). The friction factor value for fluid film regime through the gait cycle was founded variable like a consequence of UHMWPE visco-elasto-plastic behaviour. Keywords: friction factor, gait cycle, visco-elasto-plastic behaviour
Tiberiu Stefan MANESCU, Cristian Catalin PETRE, NicuSor Laurentiu ZAHARIA, Tiberiu MANESCU jr, Mihai BAYER Dynamic Tests for Fastening Rubber Plates to Determine Attenuation of Impact Loads
The railways mounting must ensure by strength and stability of the components, the guiding safety and running quality of the railways vehicles at the prescribes speeds and loads. The upper structure of the railroad is made from the ballasts, ties and rails. The steel rails mounted on ties with fastening systems, indication to maintain the railway gauge, rails inclination, stability and lasting of the railroad. Keywords: dynamic tests, rubber plates, fastening, Centipede, MGCplus
Anita-Laura Radu, Andrei Sarbu, Luminita Mara, Alexandra-Sorina Garea, Anamaria Lungu, Stefan-Ovidiu Dima, Tanta-Verona Nicolescu, Horia Iovu Influence of the Ultrasonic Field on the Template Polymerization of Acrylonitrile in Inorganic Structures
The present paper refers to the possibility of obtaining inorganic-organic nanohybrids, starting from nanoporous silica, in which the acrylonitrile template polymerization proceeds. In order to enhance the homogeneity between constitutive parts of the nanocomposite several methods were tested like increase of the imbibition period of the silica with the monomer, a better absorption capacity of the silica for the monomer and the use of the ultrasonication technique. The influence of the ultrasonic field on the template polymerization of acrylonitrile in inorganic structures was proved by FTIR and TG/DTG analyses. Ultrasonication was employed before the polymerization, in order to prevent the aggregation of particles, to well disperse the silica particles in the vinyl monomer and for a good imbibition. The results demonstrate that ultrasonication is effective in homogenizing the constitutive parts of the hybrid materials by yielding a fine microstructure of sintered nanomaterials. Keywords: inorganic-organic hybrid, porous silica, ultrasonication, template polymerization, nanocomposites
Marioara Moldovan, Adrian Almasi2, Cristina Prejmerean1, Olga Musat, Laura Silaghi Dumitrescu, Codruta Nicola, Ileana Cojocaru, Ovidiu Pastrav The Study of Some Experimental and Commercial Nanocomposites Used in Dentistry
The most appealing aspect related to nano-composites use, consists of their biomechanical properties; these properties succeed in giving good mechanical strength, a minimal polymerization contraction and an exceptional aesthetics and polish due to the features of the nano-filler. Investigating the effect upon both the filler level and the size of the filler particles on some experimental composites’ mechanical and physico-chemical properties, some authors have come to the conclusion that by increasing the filler level can be obtain first of all an increasing of the compression resistance and secondly a significant decrease of water absorption. The vast majority of the investigated composites, based on borosilicate glass, are showing an important increase of their resistance to wear together with the increase of the filler level. In this particular study the resistance to traction and respectively to fracture and also the structure (SEM) for some experimental nanocomposites (produced in our laboratory) and for a commercial product (Premise - Kerr Corporation) has been determined. The samples of material were made according to the ISO 4049 specifications; they were tested with the use of the Instron Universal Lloyd apparatus and the Scanning Electronic Microscope (SEM - FEI). Keywords: nanocomposites, physical properties, flexural strength, diametral tensile strength, SEM