Flow through tubular runners presented is a very important flow type encountered in polymer processing, especially during injection mold filling. The filling pattern developed during the mold filling plays a decisive role on the final part quality, thus, in this paper we have investigated the filling pattern and the volumetric flow rate during the filling of a tubular runner for three different materials. The melt is treated as an incompressible, non-Newtonian the Ostwald-de Waele model with a power-law relationship between the shear stress and the shear rate. Keywords: runner, injection molding, flow front, polymer melt
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The paper aims to present a theoretical-experimental approach of a particular class of composite materials known as multiphase composites in order to retrieve its effective dynamic moduli and identify the major influencing factors on these variations. Supplementary, will be presented a two step homogenization concept based on the well known theoretical predictions from the micromechanics of composite materials approaches, the Mori-Tanaka that applies to the particle reinforced composites and Halpin-Tsai that applies to the random fibre composites. The theoretical values were compared with the experimental data, the later being retrieved during a two heating cycles with temperature ranging from -300C to 1600/2000C, in air, at a frequency of 1 Hz, using a DMA 242 C device, from Netzsch, Germany. The samples were manufactured using a self-developed technology. The samples were ceramics (Al2O3) and metal (Fe) reinforced particles embedded in small volume fraction along with random E-glass fibres (65%) into a polymeric matrix material. Keywords: composites, multiphase, polymer, dynamic modulus, testing
The replacement of glass fibers polymer composites with those containing polymers and cellulose fibers, friendly for environment and human health has gained a special importance in recent years. The paper presents some mechanical and thermal characteristics of composites of neat polypropylene and jute fibers from technological wastes, treated and untreated. The use of waste fibers in polypropylene led to a significant increase of the elastic modulus and tensile strength which highlights the reinforcing effect of the waste fibers, the effect being more important in case of jute fibers treated with aminosilane. Keywords: polypropylene, composites, jute, mechanical properties
Nanoxide based composites are suitable materials for advanced medical application. Fe3O4, CoFe2O4 and MnO2 nanoparticles, synthesized by different soft chemistry routes (precipitation in the presence of soft template and solution combustion) were coated by a biocompatible polymer, sodium alginate. The oxides and corresponding composites were structural and morphological characterized. The saturation magnetization for Fe3O4-based composite is 10.1 emu·g-1, resulting magnetic domains of 5.2 nm that suggests a superparamagnetic property. Radical scavenging capability of the composites was investigated by two different methods, Trolox Equivalent Antioxidant Capacity (TEAC) and peroxide-chronoamperometry. Keywords: ferrites, MnO2 , oxide-based composites, biopolymer matrix, radical scavenger
Thin films, in the range of tens of micrometers thickness, have been prepared by casting onto glass plates the N-methyl-2-pyrrolidone solutions of two poly(ether imide)s containing isopropylidene or hexafluoroisopropylidene groups. The polymers have been synthesized by solution polycondensation reaction of 4,4’-(1,3-phenylenedioxy)dianiline, with 2,2-bis[(3,4-dicarboxyphenoxy)phenyl]propane dianhydride or 1,1,1,3,3,3-hexafluoro-2,2-bis[(3,4-dicarboxyphenoxy)phenyl]propane dianhydride. The dynamic mechanical analysis and dielectric spectroscopy were employed to study thermal and electrical behaviour of polymer films. Keywords: poly(ether-imide)s, thin films, dynamic mechanical analysis, dielectric spectroscopy
The paper focuses on rheokinetic investigations on matrix of a new composite material. A simple, yet effective, experimental method has been employed to measure several parameters that can help, by resin’ viscosity measurements, in finding resin kinetic hardening parameters. As it is shown by one of our papers [1.3,4] CFRAl (Carbon Fibers Reinforced Aluminum) is a new hybrid composite under development . It has unique and promising properties, with foreseeable excellent results in applications requiring a reliable, yet light, reinforcement material that can also withstand powerful thermal shocks. Keywords: rheokinetic model, composite material, carbon fibers, bullet-proof material
Polysulfone based membranes with controlled porosity pore density, size and orientation were synthesized. The predicted pore characteristics are obtained by adding magnetite (nano or micro) particles into the polysulfone gel and the pores obtained by applying different magnetic fields. The pore density, size and orientation can be designed based on the magnetite particle concentration, on the magnetite particles size and respectively based on the angle between membrane surface and magnetite field. The pore density, size and orientation of the membranes were analyzed by SEM. FTIR was used to investigate the membrane composition and to prove the possibility of removing the magnetite particles by acidic dissolution or by extended membrane exposure to the magnetic field. The complex thermal analysis was used to characterize the thermal behaviour of the synthesized membranes. Keywords: polysulfone membranes, pore characteristics, predicted porosity and separation ability, scanning electron microscopy
This study refers to the obtaining of mortar plasters using perlite and polymer additives additions. The performed study has outlined the infuence of the polymeric additive nature and content as well as perlite addition on mortar plasters based on hydraulic binders characteristics. Keywords: mortar plasters, polymeric additive, perlite, redispersabile powders, cellulose ethers
The increasing of the field usage of high frequency (HF) welding joints technique of thermoplastic polymers gives advantages regarding productivity, quality of welded joints and high reproducibility of results. Base of experiments, this debate analyzes the main types of failure, the causes of the failure and the prevention method for HF welding of polyvinyl chloride PVC foils. Keywords: HF welding, polymers, failures
The paper proposes new structures to replace the polystyrene, which is well known to be a toxic and inflammable material, non-biodegradable, used on a large scale for residence and civil thermal insulation and for packaging. The proposed structures are intended to be light structures, easy to manipulate, easy to be cut at the sizes needed, compact enough to not be damaged during the transport or during the mounting time, easy to fix on the building walls and of course with similar thermal insulating properties as polystyrene. First agglomerated composites were proposed. The materials used in these structures are green and biodegradable, found as inserts of wood (flakes or fibers) and textiles (wool or jute) and binders as wheat flour, clay or ecological acrylic copolymers. The density and thermal conductivity coefficient were determined for each structure and compared with the expanded and extruded polystyrene values and finally the more appropriate structures were recommended. To some of the structures flakes of polyethylene were added, in order to constitute a steam barrier of the new product. The addition of the polyethylene proved to be a disadvantage for the thermal insulation property of the structure and also for its compactness and reliability. The agglomerated composites mentioned above were pressed at a normal temperature (20-22oC) and conditioned at a temperature of 40-50oC. Two other structures were also proposed in this paper for the same purpose: a sandwich one, obtained after pressing it at 200oC, containing jute, wood fibers and polyethylene granules for the core and beech wood veneers for the faces and a panelled board made of waste of polyethylene and jute core and fiberboard faces. Keywords: polystyrene, polyethylene, thermal insulation density, composites