Manufacturing of ABS P400 Solid Cellular Structures with Closed Cells by Fused Deposition Modeling as Rapid Prototyping Process.
The use of Rapid Prototyping (RP) processes in manufacturing cellular solids offers the advantages of controlling the distribution, dimensions and interconnection of cells, which influence their micro and macro-structural properties. But not all RP processes are able to build cellular solids with closed cells, this article analyzing the capacity of Fused Deposition Modeling (FDM) process to manufacture this type of structures from ABS material. Using a test part containing cubic and spherical cells, it is shown that FDM can manufacture structures with completely enclosed voids, but only for a certain range of dimensions. This approach opens new study directions such as the possibility to analyze the mechanical behaviour of this type of cellular materials with closed cells and controlled geometry, or to use them as test parts for detecting voids in injection moulded parts. Keywords: fused deposition modeling, rapid prototyping, ABS polymer material, cellular solids, closed cells
Two Stages Grain Refining of 6082 Aluminium Alloy
In this paper the experimental results obtained at grain refining of 6082 aluminum alloy are presented, using an original method which consists in insertion of refining master alloys in two stages: in the first stage the AlTi5 elaborated at low temperature, and in stage number two AlTi5B1 classic ternary master alloy. The method ensures into the solidification process, both the elements that act by stopping the grain growth (Ti) and the nucleation centers (TiB2, AlB2, (Ti, Al)B2). Keywords: prealloys, refining
Nonlinear Thermal Impedance Electrical Model for Polymers Used in Electronic Industry
The microelectronic package continues to evolve in order to improve the performance and integrate new technology such as multidie architectures, thinner substrates, increasing integration of passive components, increasing thermal design power and lead free interconnects. Package materials must be designed to enable the electrical and thermal performance requirement and to provide high-reliability performance. Maximum heat dissipation is a requirement for today’s higher power integrated circuit devices. The maximum heat dissipation is achieved by mounting active devices directly to high thermal conductivity heat sinking substrates or packages. Direct attachment requires a compatible coefficient of thermal expansion (CTE) value of the heat sink material to avoid stress failure of the IC device. In this paper, the thermal behavior of polymers used in cooling electronics with nonlinear electrical lumped elements as a function of temperature, physical properties and sizes of a heat sink element were modeled. Keywords: high thermal conductivity polymers, heat sink, safe operating area, nonlinear thermal impedance electrical model
Studies on Some Viscosity Improvers for Multi-grade Oils 2. Rheological Behaviour of Concentrated Solutions
Rheological measurements of 3; 6; 10 and 12% INFINEUM SV 260 solutions in SAE 10W mineral oil show non-Newtonian behaviour in the temperature range 313-370 K and shear rates ranging between 3 and 1312 s-1: they follow the Bingham model at low concentrations, low shear rates and high temperatures and the Herschel-Bulkley model at high concentration, high shear rates and low temperatures. KELTAN 4200 solutions in the same solvent are more viscous than the corresponding ones given by INFINEUM SV 260 and follow the Herschel-Bulkley model onto the whole studied concentration, shear rate and temperature ranges. The slopes of the lines representing the variation of log viscosity with the reciprocal of temperature increase slightly with concentration between 3 and 10% for INFINEUM SV 260 solutions and decreases for 12%. The lowest slope is given by 3% solution, followed by 12%, and the highest one by 10% solution. KELTAN 4200 solutions present an increase of slope when passing from 3 to 6% and a decrease when the concentration exceeds the last value. The lowest slope was obtained for 12% solution, followed by 3%, while 6% solution has the highest value. This might suggest that KELTAN 4200 could be a better viscosity improver for the mineral oil SAE 10W, both at low and high concentrations. Keywords: rheological behaviour of concentrated polymer solutions, viscosity improvers, multi-grade oils
Organic Coverings Based on Powder Dyes. VIII. The influence of Splice Agents
The organic coatings made with powder dyes constitute an alternative solution to liquid dyes, for thez ensure a proper equilibrium between performance, price and work protection. Depending on the utilization field, this kind of organic coatings may be realized with different degrees of shine, from dull to glossy. In practice there are preferred the dull coatings because the surface defects of the cover films (needle shots, craters, scratches) are less visible on this type of surfaces. In this paper it was analyzed the possiblity of using as a splice agent a carboxyfunctional polyester and it was emphasized the influence of this splice agent on some characteristics of the epoxy-polyesteric powder dyes of white signal type and of cover films made with them. Keywords:organic coatings, powder dyes, splice agent, cover films
A Comparative Numerical Study Regarding the Behaviour of Some Biocompatible Plastic Materials to Injection Moulding.
This paper presents a comparative numerical simulation of an injection moulding process in the case of an acetabular cup, a basic component in a hip prosthesis, made of UHMWPE (GUR 5113, GUR EP 4224, Novatec PP BC4Y 46420) in order to determine the optimal conditions for injection process parameters. The numerical simulation was performed using fusion finite element Moldflow Plastics Insight software especially designed for injection moulding. Keywords: biocompatible materials, hip prosthesis, injection moulding, acetabular cup
Composites Based on Thermoplastic Matrices and on Termosensitive Reinforcement Materials
This paper presents the obtaining of some composite materials using wood waste (wood chips) and polymer. As thermoplastic matrix, a copolyamide polymer having a low melting interval (125-135°C) was used. Composites were obtained using a two-stage technology: a) wood-polymer pellets obtaining by melt mixing the components; b) composites obtaining by moulding the pellets into a heated press. The influence of wood content on composites properties was studied. Morphological details (by optical and electronic microscopy), thermal behaviour (through TGA and DSC analyses), mechanical properties (tensile, bending and impact strength) and behaviour towards water were investigated. It was concluded that, for a wood content higher than 40%, mechanical properties are getting poorer. Still, even the bending strength is decreasing, it remains 2-8 times higher than that of the composites based on polyolefinic matrix and wood chips. Keywords: composite materials, thermoplastic matrix, copolyamide polymer
Studies on Some Viscosity Improvers for Multi-Grade Oils 1. Solubility Parameters
The global and partial solubility parameters and radii of interaction spheres of two copolymers recommended as viscosity improvers for multi-grade mineral oils – INFINEUM SV 260 and KELTAN 4200 – were determined from solubility data and intrinsic viscosities using 13 solvents both by the classical Hansen’s method and an improved one. The obtained results are in good agreement each other and with intrinsic viscosity data. The values of the intrinsic viscosities obtained using the mineral oil SAE 10W as solvent, for which the two copolymers are intended to be used as viscosity improvers, show that it can be considered practically a very good solvent for INFINEUM SV 260 and a good one for KELTAN 4200. Keywords: multi-grade oils, viscosity improvers, global and partial solubility parameters
Liquid Crystalline Thermosets from 4,4¢-Biphenol
Liquid crystalline thermosets with biphenyl mesogen in the main chain were prepared by the curing reaction of diglycidyl ether of 4,4¢-biphenol (DGEBP) in presence of methylene-di-chloro-diethylaniline (MCDEA) and 2-amine-biphenyl (2-ABP), used as the curing agents. The product obtained by the curing reaction of DGEBP/MCDEA mixture is characterized by a texture of smectic-like structure. The curing reaction of DGEBP/2-ABP mixture led to a nematic-like structure on temperatures placed in the range of l58 - 1630C. The nematic-like texture obtained for the DGEBP/2-ABP mixture is instable at temperatures higher than 170oC. Keywords: epoxy, liquid crystal, curing, mesophase