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The paper aimed to reveal, qualitatively and quantitatively, the modifications suffered by the PLA during the complex heating cycle specific to the 3D printing followed by laser marking. The obtained results showed that the melting point of the PLA decreases from 162.2oC (which is specific to PLA filament) to 153.1oC after the 3D printing process and to 149.7oC after the laser heating. The glass transition suffered the same lowering after the printing process but an important increasing after the laser heating. The elastic modulus evolution proved a decreasing of the plasticity and that is hapenning when the material suffers an increasing of its rigidity. The elongation viscosity was analyzed and its values were decreasing with the increasing of the temperature that happened on the material. The decreasing was produced by the reduction of the elasticity, when the chain branches are decreasing their length. The decreasing is more pronounced with the increasing of the temperature. The ratio between the loss modulus to the storage modulus and quantifies the way in which the PLA absorbs and disperses energy moves its peak from 65oC (curve specific to the PLA filament) to 45oC (curve specific to the last layer deposited by 3D printing process and re-heated by laser beam for marking). The peak means the lowest storage modulus, which is a measure of elastic response of a material, so the transition from glass to high elasticity moves to the lower temperatures.

Bisphenol-A (BPA) is widely spread among the endocrine-disrupting chemicals (EDCs). Different hormone derivates or various organochlorinated pesticides are industrial human-made “plastics.” EDCs are ubiquitary used in the modern world, and their impact on human health has been intensively studied in the last decades. BPA is used as a representative model for endocrine disruption mechanisms; it represents a critical element of producing polycarbonate plastics and epoxy resins, necessary for the manufacture of beverage or food containers, various personal-care products or dental industry products. Environmental exposure to BPA or other EDCs has resulted in functional or morphological drastically alterations of the genital tract or mammary gland that lead to earlier onset of different diseases, reduce fertility, or inducing prostate cancer. All the above have been observed via multiple in vitro analyses on human cells or in vitro analyses on animal models, especially rats. BPA causes prostate cancer through a sum o mechanisms. It increases the activation of various signaling pathways (Erk or Akt kinase), steroidal receptors recruiting chromatin, derived activity of different histone-modifying enzymes, transcription of various androgen receptor mutants detected in prostate cancer or acting via a pro-inflammatory mechanism that leads to prostate cancer progression once installed. Other EDCs such as different dioxins, cadmium, or inorganic arsenic are also incriminating in the neoplastic transformation of the prostate. This review aims to evaluate the current knowledge on this topic. Most of the authors agree on the carcinogenetic effects of these compounds. Extensive in vivo research on humans is imperative for a better and more accurate understanding of “plastics” impact.

In this paper it is presented a comparative theoretical study - performed by finite element analysis (FEA), of the tension state that appears at the level of the spine, as well as in the areas adjacent to it, under the following conditions: a) the existence of a comminutive fracture at the level of the vertebra T11; b) of the external immobilization of the body through a Lombax orthesis (LO) or of the internal immobilization of the column by means of a spinal fixator (SF); c) of performing some basic flexion or extension movements. In this study, both flexural force and extension force varied on three levels. The results of the comparative theoretical study were supplemented with the clinical observations obtained from a number of 52 patients who had suffered comminutive fractures in the T11 vertebra and who were treated - by external immobilization, in the Lombax orthesis or were surgically treated - by applying a trapped spinal fixator on the T10-T12 vertebrae. The study had demonstrated that, by immobilizing the body in the Lombax orthesis, following the application of the flexion or extension movement, the mobility of the body is low, the bone fragments move less distances by about 12% against to their displacement under the condition of immobilizing the column by a spinal fixator. Although, in the latter case, the displacements of the bone fragments are greater, the elastic behaviour of the spinal fixator determines the returning of the fragments and of the spine to the initial position as well as the distance between the vertebrae. Clinical investigations on patients treated by external immobilization of the body in the Lombax orthesis show that the values of the local kyphosis angle (LKA) are about 30% lower than the values of the same parameter obtained under the surgical treatment.

The concept of ballistic protection is a subject of great importance and is defined as representing all the capabilities of the military vehicle to withstand attacks, in order to ensure protection of the crew during the missions. The projectile-plate impact research must answer a series of questions on designer or fighter behalf, among which the most important would be whether the bullet penetrates or perforates and whether the velocity after the perforation ensures a lethal effect on the personnel. The current paper presents the numerical evaluation of the working together of aluminum layers with plastic materials in a multilayer structure with honeycomb core, on impact with a rigid projectile. Plastic materials have revolutionized many industries and they are increasingly used due to their main properties, low mass and high strength. The research included the use of plastics, the positioning within the panel and the study of the two constructive versions of the structure, with coupled and uncoupled layers. Post-processing model and interpretation of the results are offered and these could be enriched and customized for other situations, similar or less similar, implicitly, the method is provided, finding a quick answer to certain questions.

With a wide range of composite resins available today, clinicians can benefit from knowledge of the infrastructure of a particular material in order to determine which type will work best in a specific clinical situation. The purpose of this study is to analyze the biomechanical behavior of four types of composite resins, two of them used in direct restorations and the other two for prosthetic restorations created in the lab.The deformations, hardness and elasticity were analyzed under the same conditions, namely at 200 Mpa, as these are very important parameters for the biomechanical behavior of the analyzed biomaterials, the specificity elements being correlated with the biomaterial structure, polymerization time and polymerization modality. As a synthesis of the biomechanical behavior outcome related to the used resins versus the resins used in the lab of dental technique using indirect means, a relatively wide range of higher value parameters stands out with regard to resistance for the lab composites compared to those used in direct restorations.

A very common questionnaire, used to evaluate the health status of Chronic Obstructive Pulmonary Disease (COPD) patients, COPD assessment test (CAT), was applied to finding correlations between the items of CAT and other tests used in the same category of COPD patients. A sample of 56 male COPD patients, aged between 51 and 74 years, mean 63.86 (±5.55), half of them receiving long-term oxygen therapy, using transparent, hypoallergenic plastic masks or nasal cannulas, answered to CAT mostly choosing single items, statistically significant correlated with the Hospital Anxiety and Depression Scale scores (HADs), like walking up hills and stairs (r = 0.412, p[ 0.01), doing activities at home (r = 0.329, p[ 0.01), confidence leaving my home (r = 0.409, p[ 0.001), sleep (r = 0.277, p[ 0.01), and energy (r = 0.387, p[ 0.01), but CAT item walking up hills and stairs correlated better to 6 min walking distance (6MWD) (r = -0.581, p[ 0.01). The most significant correlations were found between 3 items of CAT as walking up hills and stairs, limitations doing activities at home and confidence leaving home in a most powerful and depression scores and 6MWD.

Environmental problems that arise from acidic water containing aluminum generated from condensing thermal power plants can be suitably solved using membrane processes. In this paper, simultaneous neutralization with aluminum ion separation, from acidic waters containing aluminum traces, through permeation with polypropylene with inclusions of cellulose derivatives (PP / CellD)capillary composite membranes is approached. Cellulose derivatives considered are: acetylcellulose, carboxymethylcellulose, 2-hydroxyethyl cellulose, methyl 2 hydroxyethyl cellulose. The optimum working parameters for the best performance of composite membrane based on carboxymethylcellulose were determined: operating time and pH of the receiving phase. Simultaneously with the quantitative removal of the aluminum ions, it is obtained an almost neutral pH purified water, compatible with the natural waters in which it can be dispersed.

The change of the organic bone cements’composition (COO) determines the adjustment of some important properties for the behaviour as fixing material, such as the: superficial tension, polarity, surface energy, viscosity, contraction at polymerisation, porosity. In the present paper we monitored the influence of the composition’s changes for some acrylic cements upon their handling features. The samples were obtained via the partial replacement of the methyl methacrylate (MMA) in the liquid phase of some usual formulas with another acrylic monomer. For these, it was measured the contact angles as wettablility of the fixing material. Moreover, it was estimated the values of the hardening time, important parameter for the application phases of the cements with cold hardening and fixing of the articular endoprostheses.

The purpose of this experimental laboratory work is to obtain composite membranes having carbon and gold nanoparticles in the matrix. Consideration was made of using graphene oxide, a material which, under certain conditions, can generate membranes by a self-assembly process under vacuum in an aqueous or organic medium. The cellulose acetate (CA) - graphene oxide (GO) composite membranes have been functionalized with gold nanoparticles (AuNP) by two technological processes: thermal evaporation and ultrasonic mixing of stable graphene oxide and gold suspensions. The stable suspensions containing gold nanoparticles were obtained by chemical reduction of aqueous solutions of Tetrachloroauric acid trihydrate (HAuCl4) precursors with sodium citrate under high temperature conditions. Dispersibility of carbon nanostructures and precious metal nanoparticles has been studied with a DLS granulometer - Malvern Instruments Zetasizer ZS90. It was determined the mean particle size and Zeta potential function of the suspensions pH. The graphite based membranes were further subjected to various characterizations techniques. It was found that both the surfaces and the cross-sections were functionalized with gold particles. The presence of Au particles was revealed both on the membrane surface and also inside its structure. Hydrophilic tests demonstrate that the membrane filters have potential to be used in various applications.

A facile and inexpensive approach was established to prepare spherical molecularly imprinted polymers with hypericin (H-MIPs) via the wet-phase inversion method. The H-MIPs were characterized by infrared spectroscopy and thermogravimetric analysis. High-performance liquid chromatography combined with UV–Visible spectroscopy were used to assess the efficiency of the extraction procedure and, furthermore, to investigate the recognition properties of the H-MIPs. Obtaining an imprinting factor of 3.38 for hypericin strongly indicated a successful formation of molecularly imprinted cavities onto the H-MIPs. A fair selectivity towards hypericin was tested in comparison to the interfering molecule pseudohypericin.