Natural Polymeric Beads for Encapsulation of Stellaria media Extract with Antioxidant Properties
Natural polymers are biodegradable and biocompatible and can be used as carriers of pharmaceutical active compounds, with good results for the enhancement of their stability characteristics.Plant extracts of the Cariophyllaceae family are of great interest due to antioxidant, anti-inflammatory, carminative, anticancer, antibacterial, antifungal, antiviral properties, and more recently, the ability to inhibit intestinal carboxylation and reduce obesity by complex mechanisms.The aim of our study was tocharacterize the Stellaria media aqueous extract from the point of view of total polyphenols (using Folin-Ciocalteu method) and antioxidant capacity, as well as the efficiency of inclusion of Stellaria extract in calcium chloride alginate beads by two different methods. In the same time, the size of alginate microcapsules was investigated along with the released efficiencyfrom the polymeric matrix in different biological fluids.Two different methods for encapsulation of Stellaria media extract were developed in this work, using calcium alginate beads. Encapsulating efficiency shows a better approach within the method in which the extract was in situ encapsulated in “pearls”-shaped beads.
Thermal Analysis of Polymer Blends
One of the major disadvantages of epoxy resins when they are used to impregnate a fabric or when they are used to obtain laminates is their rigidity that leads in loading conditions to the matrix fracture followed by breaking of fabric due to a shearing mechanism in which the two free parts of the matrix fracture acts as a scissor. During the design of a composite material or structure such behavior of the matrix has to be taken into account and the problem could be solved if the rigidity of the matrix is reduced. The present study is about changing the value of this parameter by using an organic polymer solvent and a thermoplastic polymer to modify the basic properties of an epoxy resin. At this time an analysis of thermal properties of polymer blends is done to determine the effect of solvent and thermoplastic polymer presence inside the epoxy matrix.
Decreasing the Mass of Turbomachinery Subansamblies Using Advanced Polymer Composites
The extension of use of light advanced polymer composites from structural parts of an aircraft to all kinds of components of the engine is presently very limited by the knowledge of both technological development process and materials behaviour during service. The paper comes to meet an area of interest for many researchers and large integrators and manufacturers, by presenting the first steps made into the manufacturing of a carbon fiber reinforced composite blades for a centrifugal compressor impeller. An existing metallic reference impeller was redesigned, air flow studies were achieved to establish new design performances, precursors (type, volume fraction, architecture, distribution) were defined for the CFRP (Carbon Fiber Reinforced Polymer), stress analyses were performed on proposed structural materials configurations. Furthermore, the paper award an important section to manufacturing process stages, the manufacturing technology used and first developed trials. It was concluded that an entire impeller CFRP (Carbon Fiber Reinforced Polymer) manufacturing can and shall be the next step of the study, using autoclave technology.
Tensile and Shear Breaking Force of the Joints Between Stainless-Steel Orthodontic Bands and Buccal Tube Attachments Joined by Laser and TIG Welding Without Filler Material
Orthodontic appliances usually require the joining of different stainless-steel parts in order to achieve adequate control over tooth movement during the active treatment. The aim of this study was to assess the tensile and shear breaking force of the joints between forty orthodontic bands and forty attachments (buccal tubes), joined by laser and TIG welding, without filler material. For the laser welding technique, we used an XXS Laser (OROTIG) welding unit and for the TIG welding technique, a PUK D2 (LAMPERT) welding unit. The tensile and shear breaking force of the welded joints was determined using the Z010 Zwick/Roell testing machine. The independent-samples t-test showed statistically significant differences between the laser and TIG groups for both the tensile and the shear breaking force tests, the laser welded samples having better mechanical strength than the TIG welded samples. For practical use, under normal loading forces, both techniques are suitable for this particular application in orthodontics. In patients with parafunctional habits, that could develop higher bite forces, the failure of the welded joints might occur if the welding surface is not increased, especially for the TIG welding technique.
Copper Based Bulk Metallic Glasses for Medical Devices
Bulk metallic glasses (BMGs) represent a viable alternative for replacing classic materials used in medical devices. This paper presents the research conducted in order to obtain copper based BMGs using two different chemical compositions: Cu48Zr47Al5 and Cu45Zr45Al5Ag5. The samples were obtained by copper mold casting and their structure and properties were investigated using X-Ray diffraction (XRD), differential scanning calorimetry (DSC) and optical microscopy.
Tensile Analysis of Fabric Reinforced Materials
The analysis of reinforced polymers is one of the most important sources of information for materials properties designers. In this regard, due to their intrinsic properties, the fabrics play an essential role when they are used as reinforcement elements. The composites properties can be designed by alternating various types of fabrics, by modifying the orientation of every reinforcement layer, by modifying the matrix properties or by choosing the matrix. This study regards the tensile behavior of four fabric reinforced composites with four different epoxy resins as matrix. All the materials have the same reinforcement structure but the matrix is, in each case, another epoxy resin and more two classes of materials had been studied one is containing the natural polymerized matrix materials and the other one the materials that had been thermally treated according to technical sheet of each polymer. The tests were done one year after the materials formation.
Polyurea-based Hybrid Composites for CBRN Protection
Either considering chemical munitions or chemical improvised explosive devices, the armies should be able to counter their effects from two different perspectives: the agent used and the way to disperse it. While the agent to be delivered can be more or less lethal, the real factor that gives efficiency to the attack is the manner the agent is delivered. The state-of-the-art tested garment indicate that current knowledge regarding protective equipment for chemical warfare agents remains very limited. In this context, the present study aimed at the possibility of using the MWCNT-OH-based polyurea-composite material, obtained by our group in a previous study, in the field of protection against hazardous chemicals.
From Plastic to Fuel - New Challenges
The increased demand for energy sources is the driving force to convert organic compounds into alternative fuels. Plastic waste disposal affects the environment, since they are not easily recycled and, during the recycling process, they can produce waste ash, heavy metals, or potentially harmful gas emissions. In the plant design for plastic converting into fuel, the chemical reactor is one of the advanced equipment in the field of chemical and process engineering. This study emphasizes the feasibility of pyrolysis process for valorisation plastics by producing energy-efficient products. In this respect, samples of polypropylene, polyethylene and polystyrene were used as models and subjected to pyrolysis processes at 450 °C, in the presence of two types of mesoporous silica materials, MCM-41 and SBA-15, using a modern developed reactor. The use of mesoporous materials increased the calorific value of the obtained oil and gas, thus improving the economic potential of the process end products. This study dealt with the extraction of oil from plastics termed as plastic pyrolysis oil (PPO) and plastics pyrolysis gas (PPG), with a composition rich in different types of hydrocarbons and they can be marketed at much cheaper rates compared to that present in the market.
Plasticulture: Diffusion of Plastic Materials in the Agricultural Sector
For more than half a century, the use of plastic in agriculture has given farmers opportunities for growing fruits and vegetables regardless of the season, and at the same time achieving better quality compared to open-field cultivation. The use of plastics, through various specific techniques, helps reduce the consumption of various resources such as water, energy, fertilizers or pesticides.We could say that without these plastics a significant amount of cultivated fruits and vegetables could not be harvested in early conditions and could not be preserved and conditioned in controlled parameters.Plastic is a very important material for economy but also in everyday life. The use of plastic in agriculture has increased from year to year, thus contributing to both the increase of agricultural production and the improvement of the quality of food.Plastics are a wide range of synthetic or semi-synthetic materials that are used for various purposes. In the plastic industry, are used raw materials, such as cellulose, coal, natural gas, salt and, of course, crude oil. Plastics are extremely versatile materials and are ideal for a wide range of applications for industry as well as for consumers.
Mechanical And Thermal Behavior of Carbon Nanotubes/Vinyl Ester Nanocomposites
Single walled carbon nanotubes (SWCNT) and multi walled carbon nanotubes (MWCNT)/ vinyl ester nanocomposites with three different contents of carbon nanotubes (CNTs) have been prepared by the simple melt-compounding method. A fine and homogeneous dispersion of CNTs throughout vinyl ester resin has been noticed by SEM images. Two mechanical tests (compression and three point bending test) show that, compared to neat vinyl ester resin, compression modulus and compression strength of the nanocomposites have been significantly improved by about 9% and 14%, respectively, when incorporating only 0.15 wt.% MWCNTs. Furthermore, thermal behavior of SWCNT and MWCNT/ vinyl ester nanocomposites has been investigated and discussed based on differential scanning calorimetry (DSC) and thermo- mechanical analysis (TMA). Glass transition temperature (Tg) and coefficient of thermal expansion (CTE) have been increased and decreased, respectively, with increasing of CNTs content.