Abstract
This study presents new findings of the water/ethanol (ratio) influence on the aniline hydrochloride polymerization process in presence of ammonium persulfate. Water/ethanol mixtures in presence of monomer hydrochloride, as proved by the conductometric, spectrophotometric and refractometric investigations, are far from ideal solutions and promote a partitioned environment , for the polymerization process. By controlling this key parameter (water/ethanol ratio) the polymerization can be shifted from a initial dispersion process to a solution one, followed by precipitation. The associated phenomena revealed modification in terms of conversion, structure (FTIR, UV-VIS), morphology (SEM), thermal stability and doping agent retention (TGA-DTG). Keywords: conductive polymers, aniline hydrochloride, water/ethanol system, polyaniline