Volume 58, Issue 4

Abstract: In this paper we have created some composites reinforced with corn cob powder and the matrix was made by a combination between Resoltech 1050 resin with its Resoltech 1058 hardener. For the composites manufacturing, we have used the manual casting technique. For the new manufactured composites, we have determined the mechanical properties from the tensile test according to ASTM D3039: Young modulus, breaking strength and elongation at break. We have also molded samples for the compression test according to ASTM D695-15 and we have determined the breaking strength. The tensile and compression tests were made on universal testing machines. In the end, we have determined also the dynamic mechanical properties for the studied material by clamping the samples at one edge and leaving the samples unconstrained at the other edge. At the unconstrained edge we have placed a Bruel&Kjaer accelerometer which recorded the samples free vibrations. From the free vibrations recording and Euler-Bernoulli theory, we have determined the next dynamic mechanical properties: damping factor per unit mass and length, eigenfrequency, dynamic modulus of elasticity, loss factor and dynamic rigidity. From the experimental results, we have obtained increased breaking strength values for the proposed material at compression compared to the tensile test. Compared to similar materials studied in the engineering literature, we have obtained increased compression breaking strength.

Abstract: The extension of 3D printing processes for parts made of polymeric materials highlighted the possibility of manufacturing threaded surfaces through such processes. In principle, the operation of a threaded joint involves tensile forces in the threaded rod. The dimensional characteristics of the threaded surface and some input factors in the 3D printing process can influence the tensile strength of threaded rods made of polymeric materials. An experimental research aimed at the tensile behavior of a threaded joint was designed, using a plastic screw and a special steel nut. A factorial experiment was designed and implemented to identify an empirical mathematical model capable of highlighting the influence of the dimensional characteristics of the threaded surface and some of the input factors in the 3D printing process on tensile strength. The test samples from polymeric materials were manufactured by 3D printing, then subjected to tensile tests. The mathematical processing of the experimental results allowed the determination of a mathematical model that allows the inclusion of the ordering of the factors taken into account in terms of the intensity of the influence that these factors exert on the tensile strength of the threaded rods. It was found that the diameter of the threaded rod exerts the strongest influence on the tensile strength of the threaded rod obtained by 3D printing, increasing the diameter of the threaded rod causing an increase in the maximum deformation of the rod. Increasing the thread pitch leads to a decrease in the maximum deformation of the threaded rod.

Abstract: The effect of bamboo fiber content on mechanical properties, moisture permeability and light transmittance of composite membrane was studied. The results show that the tensile strength of the composite film is increased by 30%, and the mechanical properties of PVA film are improved obviously with the addition of bamboo cellulose, which can be used as a good reinforcing material of PVA matrix. Bamboo cellulose composite film is a kind of transparent material because of its high light transmittance.

Abstract: This study aims to reveal the consequence of thickness reinforcement on Fiber Laminates (Polyester Resin, Glass Fiber, Aluminum, and Bentonite) and to see if it can enhance the mechanical properties and resistance of laminates. Glass fiber reinforced polymer composites have recently been used in automotive, aerospace, and structural applications where they will be safe for the application`s unique shape. Hand layup was used to fabricate three different combinations, including Aluminium /Glass fiber reinforced polyester composites (A/GFRP), Bentonite/Glass fiber reinforced polyester composites (B/GFRP), and Aluminium&Bentonie/Glass fiber reinforced polyester composites (AB/GFRP). Results revealed that AB/GFRP had better tensile strength, flexural strength, and hardness than GFRP and A/GFRP. Under normal atmospheric conditions and after exposure to boiling water, hybrid Aluminium&Bentonite and glass fiber-reinforced nanocomposites have improved mechanical properties than other hybrid composites. After exposure to temperature, the flexural strength, tensile strength and stiffness of AB/GFRP Composites are 40 % higher than A/GFRP and 17.44% higher than B/GFRP Composites.

Abstract: The electrical properties of conductive carbon black (CB) nanoparticles (0.1wt percent) doped thin films made of poly(ethylene oxide) (PEO) filled with varying amounts of the electrolyte potassium alum salt and doped with conductive carbon black (CB) nanoparticles (0.1wt percent) have been investigated. The dependence of the activation energy of the composites on frequency, temperature, and filler content was studied using the AC impedance technique. The current research looked at how activation energy changed with frequency (200-1000 kHz) and temperature (30-55oC) for composites with varied potassium alum salt concentrations: 0, 2, 4, 8, 12, and 16 wt. percent. The activation energy (Ea) values measured exhibited frequency, temperature, and filler content relationships. According to polarization processes, the activation energy of the produced sheets decreases with the potassium alum salt content in the composite and decreases with the temperature. With increasing frequency, the activation energy of the produced thin films decreases.

Abstract: Results obtained from the characterization of three water samples (one representing the effluent of a municipal treatment plant and the two others representing surface water from the Jiu River/Romania, upstream and downstream of the effluent discharge point) are presented in this study in terms of microplastic content. The water samples were processed by successively passing them through a series of filters with the following dimensions: 5 mm, 0.5 mm (500 im), 0.1 mm (100 im) and then through some microfiltration membranes (MF) type EZ-Pak Membrane Filters (Merk-Millipore) made of a mixture of cellulose esters, with an average pore diameter of 0.45µm. In order to highlight the microplastics in the water samples, their analysis was performed as well as the solid material retained on the microfiltration membranes, by scanning electron microscopy (SEM) using a SEM Quanta FEG 250/Thermo Fischer Scientific. The results obtained highlighted the existence of microplastics in all the analyzed samples, in the known forms presented in the specialized literature: irregular planes, fibers and spheres. Their dimensions are variable, ranging between 3.2 µm and 119.5 µm for irregular plane microplastics and between 3 µm and 15 µm for spherical microplastics. The dimensions of microplastics in the form of fibers are also in the range of tens of µm and cannot be established exactly because in most cases they appear in the form of conglomerates. The treatment plant’s microplastic effluents content led to the modification of the physical-chemical indicators of the water in their natural receptor. Thus, the content of organic matter and total suspended matter in the downstream water compared to the effluent discharge point is higher than in the upstream water. The analysis of microplastics by SEM allows only their highlighting and their geometry, being a first step in the study of the pollution induced by such materials.

Abstract: Ophthalmic treatments using contact lenses are now used by more and more specialists around the world. Improving contact lens (CL) materials is a condition that is constantly evolving. Contact lens materials are usually composed of polymer hydrogel or silicone hydrogel. The materials used for night contact lenses are gas permeable and they gradual flatten the center of the cornea which decreases the progression of myopia or myopic astigmatism. The aim of this study is to identify, in correlation with the chemical interactions between structural components of contact lenses and their biocompatibility with the surface layer and microtopography of the cornea or sclera, different incidents that occur in patients who have used rigid gas permeable contact lenses. The study was performed on a group of 10 patients who had a follow-up period between 4 and 6 years, who presented regularly for eye examinations. The following clinical parameters were analyzed: ocular refraction before and after wearing night contact lenses, types of contact lens materials, appearance of corneal topography, biomicroscopic examination of the anterior segment of the eye, keratometry, ocular comfort, as well as other incidents regarding this type of lenses. Difficulties caused by wearing contact lenses at night arose due to poor hygiene and maintenance in two cases or due to interruption of lens wear in one case.

Abstract: Ureteral catheters, commonly known as double j stents according to their specific shape, are largely used worldwide with good results to assure proper renal drainage and to overpass ureteral obstacles successfully. This study deals with the aging behavior of polyurethane-based urinary catheters, explanted at different time intervals: 22 days, 29 days, three months, and eight months respectively. TGA (Thermogravimetric analyses) tests showed significant differences in the thermal behavior of polyurethane-based material, especially at eight months, where a higher thermostability was noticed. Also, the DSC (Differential Scanning Calorimetry) curves presented different shapes for the samples of polyurethane-based urinary catheters after three months and eight months. FTIR (Fourier-Transform Infrared Spectrometry) spectra gave a detailed picture of the chemical trans-formation which has occurred within the material at eight months. All the analyses gave an overview of the aging process of polyurethane-based urinary catheters and showed insights into the chemical/ physical transformations that the polymeric material suffers from prolonged usage.

Abstract: In this study, a new organic nucleating agent N, N`-bis(stearic acid)-1,4-dicarboxybenzene dihydrazide (PASH) to improve crystallization behavior of poly(L-lactic acid) (PLLA) along with the effect of PASH on melting behavior, thermal stability of PASH-nucleated PLLA was holistically reported. The melt-crystallization process illustrated that PASH as an effective heterogeneous nucleating agent could boost PLLA’s crystallization rate, but increasing PASH concentration and cooling rate conversely inhibited melt-crystallization process of PLLA in this study. With respect to melt-crystallization process, a larger amount of PASH leaded to a shift of cold-crystallization peak to lower temperature level. Isothermal crystallization revealed, in comparison to pure PLLA, that the half time of overall crystallization of PLLA/PASH was significantly decreased with PLLA containing 3 wt% PASH having the minimum t1/2= 67.3 s at 105ºC. The different melting behaviors of PLLA/PASH under different conditions were attributed to the nucleating effect of PASH within PLLA. In particular, the melting behavior at a heating rate of 10°C/min after isothermal crystallization depended primarily on the crystallization temperature. Whereas, the impact of crystallization time on melting behavior was negligible. Nonetheless, the melting behavior was influenced by the heating rate after non-isothermal crystallization. The thermal stability of PLLA was detrimental with the addition of PASH owing to a typical drop in onset thermal decomposition temperature.

Abstract: Sustainable materials made from recycled materials are an alternative to traditional materials (synthetic ones) and present a lower environmental impact. Due to the fact that natural fibers were successfully used to produce environmentally friendly sound adsorbing materials, biocomposites made from recycled polypropylene (PPR), feathers flour (FF) with / without compatibilizers (C) were obtained and characterized from the point of view of their acoustical behavior. Obtained materials were characterized also from the morphological and compositional point of view by scanning electron microscopy and thermal gravimetric analysis. All tested samples presented sound adsorption properties but the best results were obtained for the biocomposites with FF content of 10%-20%.

Abstract: Architectured structures, particularly auxetic materials, have demonstrated encouraging applications in energy absorption as they facilitate the customization of their structural response. Specific geometries of unit cells can thus be tailored for particular needs due to recent progress in additive manufacturing techniques. This paper experimentally studies how the grading of the cell unit angle of an auxetic core in a sandwich panel affects its energy absorbing capability and structural response. 3D printed sandwich panels with uniform and graded auxetic cellular core were tested under quasistatic compression. The results show that sandwich panels with graded core exhibit much better energy absorption capabilities with higher plateau stress and densification strain. This indicates that, by appropriately controlling its geometry, auxetic structures can show further potential as core in sandwich panels for energy absorption applications.

Abstract: The shape memory effect, as the most important ability of shape memory polymers, is a working property and provides the design ability to shape memory polymer features. Shrinkage and warpage are important parameters to control the dimensional accuracy of permanent and temporary shapes of an injection moulded shape memory polyurethane (SMPU) part. In this study, the effects of injection moulding parameters on the shrinkage and warpage of the permanent shape of moulded SMPU parts were experimentally investigated. The parameters of injection pressure, melt temperature, mould temperature, packing pressure, packing time, and cooling time, were chosen as the injection moulding control factors. Taguchi’s L27 orthogonal array design table was used with six injection moulding parameters and their three levels. The results showed that the part has different shrinkage ratios in three main directions, namely, the flow direction, perpendicular to the flow direction, and the direction through the thickness. The results of the analysis of variance showed that the cooling time is the most influential parameter on both the shrinkage (except in thickness) and warpage. The shrinkage in the flow direction as well as in perpendicular to the flow direction decreased with increasing the cooling time. Warpage also decreased with increasing the cooling time. Injection pressure and melt temperature were found to be effective on shrinkage in thickness. Effects of mould temperature, packing pressure, and packing time were found to be limited. A statistically significant relationship has been noticed among shrinkage, warpage, and residual stresses during the study.

Abstract: The aim of the paper consisted in the development of an injection mold for plastic horn cover parts in commercial vehicles. Three mold types were designed in anticipation of the structure and quality of molds, and injection molding numerical analyses were conducted for the three types of molds. One mold type was selected in consideration of the resin flow patterns inside the mold, surface quality, and final deflection amount of the horn cover. To perform optimal injection molding using the selected mold, optimization of injection molding parameters was performed using the Taguchi method, one of the designs of experiment (DOE) and ANOVA methods. As a result, it was confirmed that the deflection amount of the molding under optimal molding parameters decreased by about 34.3% compared to the deflection amount before optimization of the molding parameters. Based on these encouraging results, the previously selected mold type was actually manufactured. The horn cover was molded using the obtained optimal injection molding parameters to the manufactured mold. To verify the precision of the molded horn cover, the deflection amount of the molding was measured with a 3D scanner. The deflection amount of the horn cover was estimated to be about 11% to 43% larger for each measurement position than the deflection amounts in the analysis results. The manufactured mold was revised to solve the problem that the deflection amount of the actual molding is larger than the deflection amount predicted by injection molding analysis. The dimensions and surface quality of the horn cover with a revised mold were satisfactory.

Abstract: The goal of this research is to carry out a 3-dimensional finite detail approach evaluation of a composite plate cracked under thermal loading. The results of the mechanical properties of the composite, the orientation angle of the fibers, the geometric form of the plate, the thermal loading and the crack length had been studied to show their influence on the variation of the integral J. It is concluded that the integral J increases with the increase of crack size, temperature variation and reduce in fiber orientation perspective (e). To complete the work a probabilistic analysis was carried out.

Abstract: In this study different type of composite coatings was obtained by electrodeposition using zinc as matrix and polymeric particles as disperse phase in zinc sulphate electrolyte. The effects of some electrodeposition parameters on the thickness and morphology of obtained composite coatings were analysed by optical microscopy, Scanning Electron Microscopy (SEM) and Energy-Dispersive X-Ray Spectroscopy (EDX) methods. Polymeric particles inclusion into zinc matrix was correlated with imposed electrodeposition parameters. It was observed that the thickness of the coatings is influenced by electrodeposition parameters. From the morphology of the coatings, it could be concluded that pure zinc has a regular surface with hexagonal crystals, while the composite coatings have fine surface structure. Also, the electrodeposition parameters influence the inclusion of the dispersed phase into metallic matrix that will influence further the different properties of the composite materials.

Abstract: A study on the static analysis of a naval panel made of composite sandwich materials is presented. By using FEM, the modeling of a naval floor with a length of 5 m and a width of 2.5 m is performed. Two distinct cases, have been performed: the first model consists of the plate and stiffeners made of steel and the second model concerns a panel made of composite material sandwich type steel / SANFoam103 / steel, and the stiffeners made of steel. A parametric study has been performed. The thickness of the steel faces have 6 mm, and for the core of SANFoam have been selected the thicknesses 5 mm, 10 mm, 20 mm, 40 mm.

Abstract: Resin Concrete uses polymeric resin to replace cement concrete. Four types of polyester resins were identified with Methyl methacrylate as catalyst, calcium carbonate and fly ash as fillers along with river sand and coarse aggregate size of 10mm, 6mm were used to produce resin concrete. Seventy-two trial batches were carried out for preliminary investigation targeting compressive strength of more than 80 MPa (11.6 ksi) and four batches were shortlisted. These four batches along with the addition of glass fiber were taken for detailed investigation of stress strain behavior, young’s modulus, Poisson ratio, various correlative equations among their mechanical properties and durability properties. Developed mix can be recommended for manufacturing various polymer products.

Abstract: The usage of seals in several applications like aircraft engines is mostly made of Fluorocarbon (FKM) elastomer. They are coloured products that enable easier identification based on the applications. In such seals, fillers like carbon black cannot be added to reinforce and improvise the mechanical properties since carbon black does not make it possible to add colours. The properties after ageing are also very critical in sealing application, and they must also be improved. Also, Nanocomposites are the modern and growing trends in the field of polymers that show enormous changes in the properties of the polymers without affecting their basic properties. So, the need for improvisation of FKM seals and the concept of Nanocomposites can be merged to form FKM Nanocomposites with Nano clay and Nano silica as the fillers. The objective of this project is to improve the mechanical properties, better retention of properties after ageing and after fluid interaction of the FKM seals with the aid of Nanofillers. Different proportions of FKM nanocomposites were prepared using modified Nano Kaolin Clay & modified Montmorillonite clay (Cloisite grades). Various mechanical properties like tensile strength, tensile modulus, elongation at break, compression set and tear strength etc., were studied. The test results have shown good improvements while increasing the filler loading. This is helpful to manufacture seals of desired colours thereby avoiding the difficulties faced in the carbon black-filled FKM compounds.

Abstract: The present paper is aimed at studying the in-plane shear response of a flax fiber - epoxy resin composite laminate. Rectangular specimens, with ±45° laminate orientation with respect to loading direction were used for the experimental procedure. Tensile testing up to failure allowed to extract the shear strain-shear stress curve, which have shown a linear domain, up to approximately 25 MPa, where a shear modulus was calculated, of 1.67 GPa and a Poisson ratio of 0.7, value which is typical for off axis laminates. Strain measurement during these tests, using Digital Image Correlation, have shown that, at high stress levels, concentrators occur in the specimen in the region of failure. Repeated loading tests have shown that the material stiffens approximately 9% when increasing loading speed, leading to conclude that a viscoelastic component of the deformation is present during loading. Repeated creep-recovery tests showed that, for longer periods of time, viscoplastic deformations appear as well, with an exponential evolution with respect to the creep duration.

Abstract: This study reports the investigation of a degraded polyethylene insert retrieved after the catastrophic failure of a mobile bearing knee implant, occurred after a traumatic event and leading to a late revision. Understanding wear mechanisms of polyethylene components is important to improve the implants for joint replacement. This model of unicompartmental arthroplasty, due to its mobile, congruent insert and design, has the potential to attain low rates of wear, leading to an improved survival of the prosthesis over fixed-bearing knee implants. During the surgical technique, however, it is critical to avoid any source of impingement or incongruent articulation, as this are associated with increased rates of polyethylene wear and may contribute to the early necessity for revision surgery. The investigated insert presented a macroscopic fragmentation, surface and bulk defects and debris. Characterization of the retrieved polyethylene implant fragments was performed by macroscopic examination, by scanning electron microscopy and Fourier transform infrared spectroscopy. Due to a systematic retrieval analysis according to current standards, we can question that, in our case, third body wear is rarely pure bone or pure cement debris related but a combination of the two mentioned. The combination enhanced contribution of polyethylene debris in severe wear initiation and progression. Complete examination of the explants exhibiting breakage or severe wear may help in understanding pathogenic ways of failure in unicompartmental knee.

Abstract: The aim of this study is to investigate the effect of polishing with different solutions on the surface roughness and hardness of two different polymethylmethacrylate temporary restoration materials. In the study, two different temporary crown materials prepared in the CAD / CAM system and prepared by the traditional method were used to test a total of 224 pieces of 10 mm diameter and 2 mm thickness. After the surface roughness and micro hardness values were measured, samples were randomly divided into seven groups among themselves; After waiting 24 h, 1 and 3 weeks, values were measured again. Data were evaluated using 3-way analysis of variance (ANOVA) and Tukey HSD test. The temporary restorative materials` surface hardness and roughnesses are important to be able to stay in oral cavity without any changes. And it is also important to determine which of the materials (prepared by temporary conventional materiels or by the CAD/CAM) are less effected by the liquids in oral cavity.

Abstract: High and low density polyethylene materials constitute about 48% of total weight of plastics waste in Europe, that depends on the frequent use of these materials in packaging applications. This paper analyze the recycling effect on the mechanical properties of high and low density polyethylene (HDPE and LDPE). A mechanical recycling process was tested for the plastics waste of high and low density polyethylene, then a tensile and impact tests were performed on different mixing ratios for each of the both materials ranging from 100% of the virgin material and up to 100% of the recycled material with a difference of 10% of the sample to the other. This paper discusses the tensile properties of tensile stress at the fracture, elongation and modulus of elasticity and the impact test results for HDPE and LDPE were compared with each other.

Abstract: Kenaf is a nonwoody fibrous plant, and its fibre can be potentially used as a reinforcement in the matrix to produce biocomposite materials. The properties of biocomposite materials are highly dependent on the reinforcing material and the matrix used as a binder. This study used kenaf fibre as a reinforcing material with different compositions (10, 20, and 30 wt.%) and different fibre lengths (1 cm and 3 cm) in the matrix using the casting process. Low viscosity epoxy resin (635 thin epoxy resin) with a viscosity of 6 poise was used as the matrix. The results showed that the highest flexural strength, impact strength and shore hardness were obtained at a 30 wt.% kenaf fibre composition with a 1-cm kenaf fibre length, namely, 85 MPa, 338 KJ/m2 and 98 SHD, respectively. The length of the fibre in the matrix affects the mechanical properties of the resulting biocomposite. This condition is caused by kenaf fibres with a length of 1 cm being more dispersed in the matrix than fibres with a length of 3 cm.

Abstract: Glass reinforced plastic, so called GRP, is a composite material made of glass strands called fibbers woven together to create a flexible fabric. GRP is a lightweight material with many and diverse applications ranging from the manufacture of reservoirs for different liquids to the manufacture of boats, yachts, chairs and even children playground furniture. The behaviour of this material under static and dynamic loads is still raising interest from the scientific community and a large number of researchers. This continued interest is due to the material versatility for different applications depending on its manufacture process that has a significant weigh-in in the material mechanical properties. These resulting mechanical properties need to be carefully analysed and benchmarked prior to using the obtained material in commercial applications. The scope of this research study is to analyse the behaviour of glass reinforced plastic plate panel with reinforcements on one and two directions under static and dynamic loads employing both experimental and numerical methods for results validation. The methods used in this research study for the dynamic loads can also be applied successfully to other composite materials. Additionally, the stress plots have been analysed in iteration in order to ensure the most optimal reinforcement pattern.

Abstract: Thermoplastic materials have great usage through FDM 3D printing technology. Today, FDM 3D printer is available to the broad population, and some of the thermoplastic materials is widely used due to their small price and availability. Such thermoplastic materials are ABS (Acrylonitrile butadiene styrene) and PLA (Polylactic acid). In this paper the possibility of drone frame design optimization that can be made from ABS and PLA plastics using FDM 3D printing technology is analyzed.

Abstract: In the medical field the additive manufacturing process by fused deposition modeling has gained a great importance given the ability to create complex, organic geometries, in a short time period and the possibility of high customization. By fused deposition process the part is created layer by layer and the resulting part is characterized by high anisotropy, dictated mostly by printing parameters. To alleviate the anisotropy and to study the mechanical behavior of the 3D printed parts thermal processing is used. The materials used as filament is a poly (lactic acid) with copper particles embedded for antibacterial purposes. Samples were 3D printed using a commercial printer, thermally processed and tested in compression. On the failed specimens fracture investigations were performed to understand mechanical behavior during compression. The mechanical characteristics showed improvement and the anisotropy decreased as the processing temperature increased, but the samples became brittle. The mechanical behavior changed drastically on the thermally processed samples because of structural changes: a discontinuity between exterior layers and infill layers was created post layer fusion, the first region being the one stressed and failed first during tests.

Abstract: In order to place a product on the market that is completely safe for users, the manufacturer must go through certain steps: design, prototyping, execution and prototype validation through experimental methods, obtaining documents that allow to sell the product from certain public or private companies (for example homologation certificate) and series production. One of the most important steps is the validation tests of the prototype because it will depend on them that the prototype corresponds to the design requirements.

Abstract: Obtaining parts made of composite materials through 3D Printing Additive manufacturing have fully proved their usefulness due to a number of advantages such as: the possibility to directly create complex shapes without going through the classic process of transforming the semi-finished products into finished parts through technologies which consume resources and energy and are totally unfriendly to the environment. The main disadvantage of the parts made by 3D Printing technologies is that they are less resistant from a mechanical point of view. This was solved with the emergence of the 3D printers capable of printing composite parts consisting of a plastic matrix reinforced with continuous fibers. This research focuses on studying 4 types of composite materials from the point of view of their mechanical properties: Onyx - a rigid nylon in which micro carbon fibers are inserted and Onyx reinforced with carbon, fiber glass or kevlar. Standardized specimens were made for the uniaxial tensile test and the experimental program was designed evaluating: the Elastic modulus [GPa], the Maximum Tensile stress [MPa], the Tensile strain at maximum Tensile stress [mm/mm]. The principal strains were also determined, by means of the digital image technique made using the Aramis system from GOM. The experimental tests confirm that these new materials will be serious candidates to be used in the engineering applications in various fields.