Materiale Plastice Vol 44, Issue 2

Volume 44, Issue 2

Published: 2007 Articles: 13
Research Articles
Processing Composites Materials with Polymeric Matrix
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Abstract: Due to of their physical and mechanical properties composite materials, raise many problems regarding the drilling. This article contains, a series of experimental results and an analysis of the force when drilling into composite materials with polymeric matrix and glass fiber is made. Keywords: composite material, drilling, machining
Biodegradable compounds from regenerable resources for packings
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Abstract: The films obtained through PVOH – starch compounds melt processing, are totally destroyed in nature, due to the starch biodegradability, on one hand, the water solubility of PVOH and the biodegradability of the resulted solution, on the other hand. The paper demonstrated that the utilization of compounds with proper chemical structure make possible the modification of the PVOH and starch morphology and the formation of a new one, in such manner that the resulted PVOH – starch blends have properties different from those of the blends without destructuration additives. Keywords: alcool polivinilic, amidon, compozite biodegradabile, compatibilizare prin încâlcire (“entaglement”)
Thermoplastic Composites with cellulose microfibrilis obtained through mechanical treatment
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Abstract: Renuable resources has became an important source for micro and nano fibrils preparation. Cellulose microfibrils with 1 - 10 mm diameter were prepared by mechanical treatment of wood fibers. Some properties of cellulose microfibrils and polymer composites with such microfibrils are presented in this paper. Keywords: polimer composites, microfibrils, cellulose, polypropylene
Exact Relationships in Phenomenological Analysis of Rheodynamic Relaxation / Retardation Processes in Linear Viscoelasticity of Polymer Systems II.2. Secondary Characteristic Quantities in the Case of Stress - Controlled Processes
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Abstract: The secondary rheodynamic quantities in case of stress (s)-controlled retardation processes, including the the storage, loss and absolute moduli, as well as the corresponding loss factor, are considered from the viewpoint of frequency dependence, exact relationships providing the- s - characteristic frequencies corresponding to maximum and inflection points being given for the (1,1) - standard linear viscoelastic model. The results are illustrated in natural, semi-logarithmic, logarithmic and double-logarithmic coordinate representations. Keywords: Exact relationships, rheodynamic retardation, linear viscoelasticity, polymer systems
Aspects concerning polymers behaviour under tension
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Abstract: Polypropylene or polypropene (PP) is a thermoplastic polymer, made by the chemical industry and used in a wide variety of applications, including food packaging, ropes textiles, plastic parts and reusable containers of various types, laboratory equipment, loudspeakers, polymer banknotes and vehicle components. The authors had tested the behaviour of polypropylene used in the fabrication of some vehicle components (internal part of doors, instrument panels, seat elements aso.) under axial stress in various conditions (different speed levels for the applied force, simulated damages like holes and initial application of stress cycles). Some mechanical properties of polypropylene, which permit to fix the conditions in which it can be used successfully in vehicle components manufacture have been estimated. A comparative analysis between the polypropylene versus LDPE and HDPE has been performed. Keywords: polymer, polypropylene, mechanical properties, vehicle elements
Determination through numerical computation of the designed and functional parameters of ultra acustic systems for ultrasonic welding of intelligent composite materials
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Abstract: Analytical computation of ultrasonic transducers is a very complicated task. Its framework is the theory of elastic waves propagation in magnetostrictive, electrostrictive and piezostrictive medium and a series of constraints that need to be satisfied so that the optimum vibration modes can be found out for efficient use. The use of Finite Element Methods (FEM) allows the determination and optimization of design and functional parameters of ultra-acoustic systems for ultrasonic welding of intelligent composite materials with polymeric matrix. The modeling was done individually for each component of the ultra-acoustic system. A diagram of the particle speed amplitude variation both at the top of the ultrasonic transducer and along the length of the ultra-acoustic system was obtained. Keywords: finite element method, smart composite materials, ultrasonic method
Study of the Cooling Time for the Injection of the Plastic Materials
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Abstract: The cooling time of the plastic materials obtained through injection represents a very important component of the total duration of the injection cycle. Due to this fact, the specialized literature mentions a large number of theoretical and experimental researches which make reference to the importance of the cooling speed for the economy of the injection process. This paper presents a comparative study regarding the application of more mathematical models that may permit the determination of the cooling time for a complex material obtained through injection within a mono cavity mould. Keywords: cooling time, injection moulding, plastic materials
Recovery of new inulin mixed esters as biodegradable compounds
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Abstract: This paper presents the synthesis of some new inulin mixed esters were obtained using methacryloil and palmitoyl chloride. These esters were then copolymerized with n-butyl acrylate in order to obtain plastics for everyday use with biodegradable properties. The obtained compounds were characterized using FT-IR spectroscopy, thermogravimetric analysis; also density, tensile and torsion stress were evaluated. Keywords: inulin mixed esters, FT-IR spectrometry, thermogravimetric analysis, tensile and torsion stress
Mechanical properties of epoxy resins used in compounds with insecticides
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Abstract: Mechanical properties of epoxy resin ROPOXID-501 additivated with polyethylene glycol-400 and chlorendic anhydride were studied. The behaviour of those mixtures exposed different times at UV radiation was also investigated. The added chlorendic anhydride enhances the strain at the break, the hardness and elastic energy and improves the stability at UV radiation. Keywords: epoxy resin, mechanical properties, UV radiation, additives
Stability of the flexible PE pipes buried in the ground
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Abstract: The vertically acting load of soil causes a deflection of the pipe, which in turn results in a horizontal supporting soil pressure to show up. The pipe wall will be then subjected to both compression stresses and bending stresses. As consequence, the design of flexible PE pipe buried in the ground follows quite different rules from those classically accepted for rigid pipes. The article presents the soil burial loads of flexible pipes. The short-term, the long-term maximum vertical defelction and the resistance to buckling were determined. Keywards: polyethilene pipe, buried plastic pipes, strength, buckling
Aspects concerning the degradation of the elastical and mechanical characteristics at bending of the composite materials made of E glass fibres reinforced polymeric resins because of the moisture absorbtion
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Abstract: The paper describes the aspects concerning moisture absorption on the behaviour at bending in case of composite materials made of E-glass fibres reinforced polymeric resins. These fibres were used to randomly reinforce the following resins: two polyester resins (Heliopol 8431 ATX, Polylite 440-M880), epoxy resin (LY 554) and vinyl-ester resin (Atlac 582). The first of all, experimental data concerning moisture absorption was analysed during ten months. Three different environments were considered: water, water / detergent mix and natural seawater (Black Sea). Then, the composite material specimens were subjected to the flexural test (three point’s method). The results obtained in case of the submerged specimens (9200 hours) were compared with the results obtained in case of the dry specimens. Finally, the conclusion was that the moisture absorption in composite materials tested leads to the decreasing of the flexural mechanical characteristics (elastic flexural stress se, flexural modulus E and failure energy). The paper briefly describes the laboratory tests and shows graphically the final results. Keywords: composites; moisture; flexural modulus; flexural stress; failure energy
Multiobjective Optimization of a Free Radical Polymerization Genetic Algorithms
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Abstract: The present paper continues a previous article [1] where multiobjective optimization of a polymerization process was approached with a classical method – sequential quadratic programming. In this article, an optimization method based on genetic algorithms is used for the free radical polymerization of methyl methacrylate. The influence on the optimization results of the main parameters (the size of the initial population, the number of generations, recombination rate, mutation rate), as well as that of different variants of genetic algorithms (different ways of recombination, mutation and selection) is studied. The main conclusion of the article is that these values and methods depend on the studied process, but also inter-condition each other, such that the optimization results are rather more correlated with the overall set of values considered. Thus, we try to establish some directions to guide the search for optimal values. Keywords: genetic algorithms, optimization, free radical polymerization
Considerations about Filling Materials Influence upon Deflection of Epoxy Resin under Cryogenic Conditions
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Abstract: The paper presents the methodology of determining the plasticity of some composites specimen through bending test. The equipment is presented both for room temperature testing and under cryogenic conditions. Particularities of the measurements under cryogenic conditions are specified. The influence of talc concentration in the composite material is presented. Key words: composite materials, deflection, cryogenics.