Effect of Polishing Systems on Translucency Parameter of the Resin Composites after Aging
The purpose of this study was to evaluate the effect of finishing/polishing systems on the translucency parameter (TP) of resin composites after accelerated artificial aging (AAA). Four composite resins (Filtek Z250, Admira, IPS Empress Direct, Clearfil Majesty Esthetic) were evaluated. Thirty samples were prepared with each resin composite and divided into three subgroups: control (Mylar strip), disc (Optidisc), and rubber (Dimanto) (n=10). The spectrophotometer was used to determine color measurements. TP was calculated the using the CIEDE 2000 formula. Data were analyzed using Generalized Lineer Model (p[0.05). The three factors (composite resin, finishing/ polishing, and AAA) had no statistically significant influence on the TP. However, composite and finishing/polishing influenced the TP. Filtek Z250 showed the lowest TP values and the IPS Empress Direct showed the highest TP values before and after AAA. Polished groups showed higher TP values than control groups before and after AAA. IPS Empress Direct with Dimanto had higher TP values than other groups (except for IPS Empress Direct with Optidisc); Filtek Z250 with finishing/polishing groups showed lower TP values than other groups. Composite type and finishing/polishing systems influenced TP values. Unfinished groups exhibited lower TP values than finished groups. There was no difference in TP values between finishing/polishing systems (Dimanto and OptiDisc).
Biomaterials Used in the Prosthetics of Facial Fractures
The etiology of maxillofacial injuries is represented by car accidents, human aggression, and work-related trauma. Trauma to the maxillofacial area requires a complex treatment that involves functional and aesthetic rehabilitation. To restore the functionality of the damaged areas, a correct surgical technique is necessary along with the use of the ideal prostheses for a better reconstruction. Along with the development and improvement of facial fractures osteosynthesis techniques, an attempt was made to identify the right material to complete these surgical methods. We analyze in this paperwork the benefits of polyetheretherketone-based materials in the prosthetics of different facial fractures in comparison with other materials like titanium.
Chemical and Mechanical Properties for Rosin-based Hybrid Resins
The increasing concern for the protection of the environment, through the use of renewable natural resources, has led in the last decades to the realization of a number of natural polymers or hybrids to be able to replace petroleum-based polymeric materials. Rosin is a low-cost wood resin extracted from conifers. In this paper, based on FTIR and Raman analyses, the spectra of natural Rosin resin and some hybrid resins with volume proportions of 45, 55 and 65% Rosin were studied. Some mechanical properties such as modulus of elasticity, elongation at break, tensile strength were determined from stress-strain diagrams obtained from tensile stress. Increasing the volume proportion of Rosin leads to a decrease in stiffness and strength properties and obtaining a visco-elastic behavior.
Research on the Lifting Forces of Industrial Plastic Vacuum Cups
Industrial vacuum cups are used for lifting, holding and moving a wide variety of automated applications for handling semi-finished products and parts made of a wide range of materials - metal, glass, plastic, paper, wood, etc. and are used in a variety of industries. This paper presents some of the authors` theoretical and experimental research on the maximum lifting force that different types of vacuum cups can achieve. The study was carried out on the basis of sizing recommendations made by manufacturers and dealers of these types of vacuum cups. The specially designed experimental stand was installed on the universal material testing machine LBG 100 kN and allowed the practical determination of these lifting forces provided by various types of industrial vacuum cups. Lifting force measurements were carried out with the AXIS FB 1k digital dynamometer attached to the machine. Vacuum cups of 3 different shapes and made of 3 different materials were used, using different vacuum depressions - 0.3 bar, -0.5 bar, -0.7 bar and -0.9 bar. The research aimed to determine by measurement the maximum lifting force of these types of vacuum cups applied to steel parts. The results obtained for these forces were compared with the calculated theoretical values, with the manufacturer’s recommended dimensioning values, and comparative conclusions were also drawn on the maximum lifting force provided by the different types of industrial vacuum cups studied.
Study on the Use of Digital Technology in the Realization of Prosthetic Restorations
The use of digital technology has become a useful and also a preferred process in the realization of dental prosthetic restorations, because through it, superior quality dental prostheses are obtained in terms of aesthetics, accuracy of execution and durability. CAD/CAM technology is changing all aspects of dentistry, making dental restoration processes much easier and more efficient for dentists, patients and dental technicians. The materials that can be used to manufacture dental restorations designed using Exocad software depend on the type of restoration (crowns, bridges, veneers, etc.) and the manufacturing method (milling with a 3-, 4-, or 5-axis CAM device); available materials include: PMMA (polymethyl methacrylate) and zirconia. Using digital technology, in this study we performed 6 fixed prosthetic restorations, of which 5 unidental restorations (5 dental crowns) and 1 pluridental restoration (a 4-element dental bridge); of the 6 prosthetic restorations, 3 restorations will be fixed by cementing on dental abutments, and 3 restorations will be fixed by screwing on implants. Digital technology allows the use of higher quality materials, resulting in more resistant and more aesthetic prosthetic restorations; helps reduce the occurrence of errors; obtaining a better marginal adaptation and a perfect adaptation to the anatomical structures of the patient`s teeth.
Starch Modified Tough Biocompatible Polyurethane/acrylamide bio Composites: Physicochemical Properties and Biodegradation Studies
Biodegradable bio composites with potential applications in medical implants were prepared with starch content by in situ polymerization technique using polyurethane prepolymers. (PU) and acrylamide (AAM) monomers. The structure and properties of bio composites were evaluated. FT-IR spectroscopy showed bonding between N=C=O functional group terminated polyurethanes confirmed improved compatibility of prepolymers, AAM, starch and bio composites. The DSC data are the glass transition (Tg) of the bio composite and ordinary polyacrylamide (PAAM) network. By incorporating starch and polyurethane in the form of an interpenetrating network into a polyacrylamide network, mechanical and thermal properties of bio composites due to higher crosslink density given by hard segment content. We studied the swelling behavior of both bio composites and individual PAAM networks under different pH conditions to validate their biocompatibility and potential use in biomedicine setting. The hydrolytic stability of biocomposites and PAAM networks was investigated using phosphate buffer. Hydrolytic stability of biocomposites was found to be higher comparison with PAAM network. Morphological analysis of the samples showed uniform distribution and good interfacial adhesion. Improves sample biodegradability it was revealed by the soil runoff test.
Use of Panels Made from Plastic Waste in Thermal Insulation
The materials of the given article are devoted to the problem solution associated with one of the processing plastic waste methods by adding various fillers in order to obtain the final product for the thermal insulation materials manufacture. The researches were conducted using the UPR (unsaturated polyester resin) samples made of EPS (expanded polystyrene) plastic waste and crushed recycled polyethylene from greenhouse film waste with various types of wood waste from carpentry workshops. The tests have revealed that when EPS is added to the unsaturated polyester mixtures, the EPS thermal conductivity coefficient decreases with a slight decrease in density, which gives the wide opportunities to use EPS waste as an additive for UPR and expands the ways of its potential industrial application, and the addition of styrene to the compositions containing 10% of styropor causes a clear decrease in thermal conductivity characteristics and a slight decrease in the density of these mixtures. The values of the thermal conductivity coefficient and the density of the low-density polyethylene material increase with the wood powder percentage raising used as an organic filler.
The Importance and Necessity of New Bio-Based Materials in Industrial Design
Main goals like technical innovation, costs and respect for the environment urge us to discover finer, lighter, biodegradable, and more «intelligent» materials in their functionality. The development of industrial design is motivated by criteria such as the environment, sustainability, the need for lightweight products, manufactured with fewer components and integrating various functions. As experts in new materials and technologies for the development of innovative products, we work closely with international research institutes as part of our projects. We want to create materials that combine such properties in the most efficient way, interacting with their close environment and the environment in general and, based on their features, to be transformed through various processes in completely different materials. The goal of our work is to compare different existing materials with a new bio-based material using quantifiable measurement indicators and sensory measurement indicators. The purpose of this article is to provide a few elements that can be used as a guide in establishing a quantitative impact assessment strategy based on the use of sensory evaluation techniques. In the framework of our presentation, we will focus mostly on comparing the materials via a metrological tool for quantifying tactile characteristics likely to be correlated to the `ground truth` that constitutes a sensory profile.
Mechanical Properties of Polymer-Infiltrated Fluorapatite Glass Ceramics Fabricated from Clam Shell and Soda Lime Silicate Glass
Can polymer-infiltrated florapatite glass ceramic produced from waste materials, such as clam shell and soda lime silicate glass, be used in prosthetic rehabilitation? The purpose of this study is to investigate the effect of Si/Ca ratio on the mechanical properties of Nb-Bi-Ce doped polymer-infiltrated fluorapatite ceramic networks (PICNs) produced from clam shell (CS) and soda lime silicate (SLS) glass by conventional melt-quench technique, used as a dental ceramic. PICNs comprising Si/Ca at four different weight percentage ratios: 1.27% (PICN-1), 2.15% (PICN-2), 4.12% (PICN-3) and 12.6% (PICN-4) were prepared (n=10). The powder mixtures in four different ratios were compressed in a rectangular prism shaped mold and subjected to equal pressure from all sides in a cold isostatic press, followed by heat treatment at 750C for 3 h. Then complete vacuum infiltration was done with a polymer mixture then low temperature firing was applied leading to the formation of the PICNs. Wear behavior and 3-point bending properties were evaluated and specimens were analyzed using scanning electron microscopy (SEM). The friction and wear properties were determined by means of a pin-on-disk tribotester. Since the flexural strength test did not show normal distribution, Kruskal Wallis test was performed in independent groups, p[0.05. There is a significant difference of flexural strength values between the groups (p=0.032), it was determined that the difference was between the PICN-1 and PICN-4 groups (p=0.037). In the analysis of wear scar, abrasion grooves were also observed. The results of this study showed that high Ca and Si content in CS and SLS glass, respectively, encourages the use of waste materials in the production of PICNs intended to be used in prosthetic rehabilitation. The composition of PICNs produced from waste materials affected flexural strength and wear behavior. Increasing the Si/Ca ratio was found to support the mechanical properties of experimental PICN and that experimental PICNs can be considered as high potential candidates for dental applications.
Prediction of the Dielectric Properties of Some Eco-composite Materials for Energy-related Applications
The study establishes a theoretical evaluation trough several models concerning the dielectric properties of some new eco-composites made of a cellulosic derivative matrix – hydroxypropyl methylcellulose (HPMC) – in which distinct sorts of fillers (ceramic, metallic and bio-derived) were introduced. The investigation describes the impact of the filler addition on the dielectric constant, the dielectric breakdown, and finally how these two factors are contributing to the electric energy density of purposed eco-composites. After incorporation of the reinforcement agents, the dielectric constant significantly increases comparatively with the matrix, as a function of the type of filler used. Moreover, by assessing of the dielectric breakdown, it is observed that with the increase of filler quantity, this parameter slightly decreases for all samples. The data concerning the electric energy density reveal that, by filler insertion in the HPMC matrix, an improvement occurs, especially for the barium titanate system owing to its large dielectric constant. These data are promising for design of new eco-composites having improved dielectric features as demanded for green energy storage devices. Since the materials have biodegradable and biocompatible character, they also have importance in bio-related applications.