Open Access Research Article

GABRIELA LILIANA AILIESEI, VIRGIL BARBOIU Reactions on Heteroaromatic Polymers with Amine Groups A NMR study of chemical reactions and products of poly(N–vinylimidazole)

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Published 30 Sep 2015

Abstract

Protonation, quaternization and addition reactions of poly(N-vinylimidazole) to the imidazole nitrogen atom in the position 3 to obtain the corresponding ionic derivatives were studied by NMR spectroscopy. Information and data on the reaction type and product microstructure are presented. The chain tacticity is a special structure aspect which was in detail studied by means of proton and carbon NMR spectra confirming that the chain configuration is not modified by any of the three polymer-analogous reactions. Keywords: poly(N-vinylimidazole); polyelectrolytes; benzyl chloride; trifluoroacetic acid; acrylic acid; chain tacticity; polymer microstructure

How to Cite this Article

(2015). GABRIELA LILIANA AILIESEI, VIRGIL BARBOIU Reactions on Heteroaromatic Polymers with Amine Groups A NMR study of chemical reactions and products of poly(N–vinylimidazole). Materiale Plastice, 52(3).
. GABRIELA LILIANA AILIESEI, VIRGIL BARBOIU Reactions on Heteroaromatic Polymers with Amine Groups A NMR study of chemical reactions and products of poly(N–vinylimidazole). Materiale Plastice. 2015;52(3).
, "GABRIELA LILIANA AILIESEI, VIRGIL BARBOIU Reactions on Heteroaromatic Polymers with Amine Groups A NMR study of chemical reactions and products of poly(N–vinylimidazole),” Materiale Plastice, vol. 52, no. 3, 2015.
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