Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization

Al-Mayyahi, Baqer A.; Al-Lami, Hadi S.; Haddad, Athir M.

Baqer A. Al-Mayyahi, Hadi S. Al-Lami, Athir M. Haddad

Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization

Abstract:
Novel block biocopolymers were made by copolymerizing the prepared polylactide-dipenta-erythritol macromonomer with two different monomers, N-hydroxyethyl acrylamide (HEAA) and N,N-dimethylamino ethyl methacrylate (DMAEMA), with an activator generated by atom transfer radical polymerization (ATRP), to have a different duplicating unit of 10, 25, 50, and 100. ATRP employs a copper(I) bromide (CuBr) catalyst system with N, N, N′, N′′, N′′-pentamethyl diethylenetriamine (PMDETA). Different spectroscopic and analytical methods used for characterization of the prepared biocopolymers, such as FT-IR, 1H NMR, 13C NMR, and GPC, showed that they had narrow dispersity with controllable molecular weight and were accompanied by nanostructures as examined by SEM technique on all biocopolymers, confirming the correctness of the expected structures of biocopolymers. The shape and size of the produced polymeric nanoparticles were determined using a scanning electron microscope (SEM), and they were developed using the Image-J application.

Keywords:
ATRP; dipentaerythritol; N; N-dimethylamino ethyl methacrylate; block biocopolymers; six-arms; N-hydroxyethyl acrylamide

Issue: 2022 Volume 59, Issue 2

Pages: 50-60

Publication date: 2022/7/1

https://doi.org/10.37358/MP.22.2.5584

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Cite this article as:
AL-MAYYAHI, B.A., AL-LAMI, H.S., HADDAD, A.M., Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization, Mater. Plast., 59(2), 2022, 50-60. https://doi.org/10.37358/MP.22.2.5584

Vancouver
Al-Mayyahi BA, Al-Lami HS, Haddad AM. Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization. Mater. Plast.[internet]. 2022 Apr;59(2):50-60. Available from: https://doi.org/10.37358/MP.22.2.5584

APA 6th edition
Al-Mayyahi, B.A., Al-Lami, H.S. & Haddad, A.M. (2022). Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization. Materiale Plastice, 59(2), 50-60. https://doi.org/10.37358/MP.22.2.5584

Harvard
Al-Mayyahi, B.A., Al-Lami, H.S., Haddad, A.M. (2022). 'Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization', Materiale Plastice, 59(2), pp. 50-60. https://doi.org/10.37358/MP.22.2.5584

IEEE
B.A. Al-Mayyahi, H.S. Al-Lami, A.M. Haddad, "Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization". Materiale Plastice, vol. 59, no. 2, pp. 50-60, 2022. [online]. https://doi.org/10.37358/MP.22.2.5584

Text
Baqer A. Al-Mayyahi, Hadi S. Al-Lami, Athir M. Haddad,
Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization,
Materiale Plastice,
Volume 59, Issue 2,
2022,
Pages 50-60,
ISSN 2668-8220,
https://doi.org/10.37358/MP.22.2.5584.
(https://revmaterialeplastice.ro/Articles.asp?ID=5584)
Keywords: ATRP; dipentaerythritol; N; N-dimethylamino ethyl methacrylate; block biocopolymers; six-arms; N-hydroxyethyl acrylamide

RIS
TY - JOUR
T1 - Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization
A1 - Al-Mayyahi, Baqer A.
A2 - Al-Lami, Hadi S.
A3 - Haddad, Athir M.
JF - Materiale Plastice
JO - Mater. Plast.
PB - Materiale Plastice SRL
SN - 2668-8220
Y1 - 2022
VL - 59
IS - 2
SP - 50
EP - 60
UR - https://doi.org/10.37358/MP.22.2.5584
KW - ATRP
KW - dipentaerythritol
KW - N
KW - N-dimethylamino ethyl methacrylate
KW - block biocopolymers
KW - six-arms
KW - N-hydroxyethyl acrylamide
ER -

BibTex
@article{MatPlast2022P50,
author = {Al-Mayyahi Baqer A. and Al-Lami Hadi S. and Haddad Athir M.},
title = {Synthesis and Characterization of Novel Nano Six-arms of (polylactide-dipentaerythritol)-block-N-hydroxyethyl Acrylamide and N,N-dimethylamino Ethyl Methacrylate Biocopolymers by Atom Transfer Radical Polymerization},
journal = {Materiale Plastice},
volume = {59},
number = {2},
pages = {50-60},
year = {2022},
issn = {2668-8220},
doi = {https://doi.org/10.37358/MP.22.2.5584},
url = {https://revmaterialeplastice.ro/Articles.asp?ID=5584}
}

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