Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites

Pradeeba, Shanmugam Jaiganesh; Jeyagowri, Balakrishnan; Sivakumar, Krishnaswamy; Vidhya, Lakshmana Perumal; Sampath, Krishnan

Shanmugam Jaiganesh Pradeeba, Balakrishnan Jeyagowri, Krishnaswamy Sivakumar, Lakshmana Perumal Vidhya, Krishnan Sampath

Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites

Abstract:
In this present research work, Poly(azomethine), ZnO, TiO2, poly(azomethine)/TiO2 and poly(azomethine)/ZnOnanocomposites were synthesized. Prepared nanocompositewas characterized by FourierTransform-Infrared spectroscopy, UV-Visiblespectroscopy, PowderX-raydiffraction, band gap, EDAX and SEM. The Photocatalytic activity of the samples was evaluated for the degradation of MethylorangeandAlizarin red S under natural sunlight. The effects of dye concentration were studies for the decolorization of MethylorangeandAlizarin red S. The degradationefficiency,reactionkinetics and isotherm studies revealed that the Polyazomethine /ZnO(PNZ) and poly(azomethine)/TiO2(PNT) nano-composites have shown excellent photocatalytic activity than PAZ, ZnO and TiO2.At optimum dye concentrations of 10ppm Methyl orange and Alizarin Red S shows maximum degradation efficiency was 87% and 86% usingPNZ and PNT nanocomposites asaphotocatalysts at 5 h contact time. FT-IR, UV-Visible spectroscopy, SEM and EDAX were used to describe the samples after the photocatalytic investigation. To examine the effect of decolorisation of dyes using synthesized photocatalysts Pseudo first order kinetic, pseudosecond order model, Langmuir, Freundlichisothermsstudieswere carriedout and also followed by intra-particle diffusion model, whereas diffusion is not only the rate-controlling step. The results show that the degradation capacity decreases with an increase in solution temperature from303 K to 333 K. The thermodynamics parameters were evaluated.

Keywords:
polyazomethine; photocatalyst; nanocomposites; anionic dyes; kinetic model; degradation efficiency

Issue: 2022 Volume 59, Issue 4

Pages: 48-69

Publication date: 2023/1/6

https://doi.org/10.37358/MP.22.4.5625

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Cite this article as:
PRADEEBA, S.J., JEYAGOWRI, B., SIVAKUMAR, K., VIDHYA, L.P., SAMPATH, K., Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites, Mater. Plast., 59(4), 2022, 48-69. https://doi.org/10.37358/MP.22.4.5625

Vancouver
Pradeeba SJ, Jeyagowri B, Sivakumar K, Vidhya LP, Sampath K. Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites. Mater. Plast.[internet]. 2022 Dec;59(4):48-69. Available from: https://doi.org/10.37358/MP.22.4.5625

APA 6th edition
Pradeeba, S.J., Jeyagowri, B., Sivakumar, K., Vidhya, L.P. & Sampath, K. (2022). Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites. Materiale Plastice, 59(4), 48-69. https://doi.org/10.37358/MP.22.4.5625

Harvard
Pradeeba, S.J., Jeyagowri, B., Sivakumar, K., Vidhya, L.P., Sampath, K. (2022). 'Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites', Materiale Plastice, 59(4), pp. 48-69. https://doi.org/10.37358/MP.22.4.5625

IEEE
S.J. Pradeeba, B. Jeyagowri, K. Sivakumar, L.P. Vidhya, K. Sampath, "Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites". Materiale Plastice, vol. 59, no. 4, pp. 48-69, 2022. [online]. https://doi.org/10.37358/MP.22.4.5625

Text
Shanmugam Jaiganesh Pradeeba, Balakrishnan Jeyagowri, Krishnaswamy Sivakumar, Lakshmana Perumal Vidhya, Krishnan Sampath,
Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites,
Materiale Plastice,
Volume 59, Issue 4,
2022,
Pages 48-69,
ISSN 2668-8220,
https://doi.org/10.37358/MP.22.4.5625.
(https://revmaterialeplastice.ro/Articles.asp?ID=5625)
Keywords: polyazomethine; photocatalyst; nanocomposites; anionic dyes; kinetic model; degradation efficiency

RIS
TY - JOUR
T1 - Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites
A1 - Pradeeba, Shanmugam Jaiganesh
A2 - Jeyagowri, Balakrishnan
A3 - Sivakumar, Krishnaswamy
A4 - Vidhya, Lakshmana Perumal
A5 - Sampath, Krishnan
JF - Materiale Plastice
JO - Mater. Plast.
PB - Materiale Plastice SRL
SN - 2668-8220
Y1 - 2022
VL - 59
IS - 4
SP - 48
EP - 69
UR - https://doi.org/10.37358/MP.22.4.5625
KW - polyazomethine
KW - photocatalyst
KW - nanocomposites
KW - anionic dyes
KW - kinetic model
KW - degradation efficiency
ER -

BibTex
@article{MatPlast2022P48,
author = {Pradeeba Shanmugam Jaiganesh and Jeyagowri Balakrishnan and Sivakumar Krishnaswamy and Vidhya Lakshmana Perumal and Sampath Krishnan},
title = {Photodegration of Anionic Dyes Using Polyazomethine/Titanium di-Oxide and Polyazomethine/ Zinc Oxide Nanocomposites},
journal = {Materiale Plastice},
volume = {59},
number = {4},
pages = {48-69},
year = {2022},
issn = {2668-8220},
doi = {https://doi.org/10.37358/MP.22.4.5625},
url = {https://revmaterialeplastice.ro/Articles.asp?ID=5625}
}

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