The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties

Xia, Hong-Xia; Cai, Yan-Hua; Wang, Jun; Huang, Hao; Zhao, Li-Sha

Hong-Xia Xia, Yan-Hua Cai, Jun Wang, Hao Huang, Li-Sha Zhao

The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties

Abstract:
Improving the crystallization performance of poly(L-lactide) (PLLA) is necessary to adapt for various applications. In the current work, N, N'-bis(isonicotinic acid) 1, 4-naphthalenedicarboxylic acid dihydrazide (NAIAH) was synthesized to be firstly aimed at promoting the crystallization of PLLA, and the NAIAH-nucleated PLLA materials were prepared using PLLA as a matrix material and NAIAH as a nucleating agent, and the crystalline nucleation, melting behavior, thermal decomposition and mechanical properties of PLLA/NAIAH samples were investigated by the relevant testing instruments. The results from the non-isothermal melt-crystallization from the melt of 190oC indicated that the NAIHA could significantly accelerate PLLA’s crystallization, and played an efficient heterogeneous nucleation in PLLA’s crystallization. The effect of different final melting temperatures on PLLA’s melt-crystallization behavior showed that a relatively low final melting temperature was beneficial for the crystallization of PLLA, and the 170oC was the optimum final melting temperature in this study. An increase of cooling rate could weaken PLLA/NAIAH’s crystallization ability, but the NAIAH was still able to promote PLLA’s crystallization upon the fast cooling at 50oC/min, showing a powerful crystallization accelerating effect of NAIAH. PLLA/NAIAH’s melting behaviors after different crystallization conditions were affected by heating rate and crystallization temperature, and the double melting peaks appeared in melting DSC curves were assigned to melting-recrystallization. Thermal decomposition processes in air showed that the NAIAH decreased PLLA’s thermal stability, but the interaction of PLLA with NAIAH had an inhibition for a drop in onset decomposition temperature. Additionally, the introduction of NAIAH dramatically reduced PLLA’s tensile modulus and elongation at break.

Keywords:
Poly(L-lactide); 1;4-naphthalenedicarboxylic acid; crystallization; organic nucleating agent; thermal behavior

Issue: 2022 Volume 59, Issue 3

Pages: 232-244

Publication date: 2022/10/3

https://doi.org/10.37358/MP.22.3.5617

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Cite this article as:
XIA, H., CAI, Y., WANG, J., HUANG, H., ZHAO, L., The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties, Mater. Plast., 59(3), 2022, 232-244. https://doi.org/10.37358/MP.22.3.5617

Vancouver
Xia H, Cai Y, Wang J, Huang H, Zhao L. The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties. Mater. Plast.[internet]. 2022 Jul;59(3):232-244. Available from: https://doi.org/10.37358/MP.22.3.5617

APA 6th edition
Xia, H., Cai, Y., Wang, J., Huang, H. & Zhao, L. (2022). The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties. Materiale Plastice, 59(3), 232-244. https://doi.org/10.37358/MP.22.3.5617

Harvard
Xia, H., Cai, Y., Wang, J., Huang, H., Zhao, L. (2022). 'The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties', Materiale Plastice, 59(3), pp. 232-244. https://doi.org/10.37358/MP.22.3.5617

IEEE
H. Xia, Y. Cai, J. Wang, H. Huang, L. Zhao, "The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties". Materiale Plastice, vol. 59, no. 3, pp. 232-244, 2022. [online]. https://doi.org/10.37358/MP.22.3.5617

Text
Hong-Xia Xia, Yan-Hua Cai, Jun Wang, Hao Huang, Li-Sha Zhao,
The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties,
Materiale Plastice,
Volume 59, Issue 3,
2022,
Pages 232-244,
ISSN 2668-8220,
https://doi.org/10.37358/MP.22.3.5617.
(https://revmaterialeplastice.ro/Articles.asp?ID=5617)
Keywords: Poly(L-lactide); 1;4-naphthalenedicarboxylic acid; crystallization; organic nucleating agent; thermal behavior

RIS
TY - JOUR
T1 - The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties
A1 - Xia, Hong-Xia
A2 - Cai, Yan-Hua
A3 - Wang, Jun
A4 - Huang, Hao
A5 - Zhao, Li-Sha
JF - Materiale Plastice
JO - Mater. Plast.
PB - Materiale Plastice SRL
SN - 2668-8220
Y1 - 2022
VL - 59
IS - 3
SP - 232
EP - 244
UR - https://doi.org/10.37358/MP.22.3.5617
KW - Poly(L-lactide)
KW - 1
KW - 4-naphthalenedicarboxylic acid
KW - crystallization
KW - organic nucleating agent
KW - thermal behavior
ER -

BibTex
@article{MatPlast2022P232,
author = {Xia Hong-Xia and Cai Yan-Hua and Wang Jun and Huang Hao and Zhao Li-Sha},
title = {The Application of N, N'-bis(Isonicotinic Acid) 1, 4-Naphthalenedicarboxylic Acid Dihydrazide in Biodegradable Poly(L-lactide): Crystalline Nucleation, Melting Behavior, Thermal Stability and Mechanical Properties},
journal = {Materiale Plastice},
volume = {59},
number = {3},
pages = {232-244},
year = {2022},
issn = {2668-8220},
doi = {https://doi.org/10.37358/MP.22.3.5617},
url = {https://revmaterialeplastice.ro/Articles.asp?ID=5617}
}

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