Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers

Zubizarreta, Leire; Gil-Agusti, Mayte; Espinosa, Juan Carlos; Garcia-Pellicer, Marta; Quijano-Lopez, Alfredo

Leire Zubizarreta, Mayte Gil-Agusti, Juan Carlos Espinosa, Marta Garcia-Pellicer, Alfredo Quijano-Lopez

Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers

Abstract:
In this study, two different non-ionic surfactants have been evaluated as a plasticizer in lithium polymer electrolytes and compared with an organic carbonate-based plasticizer. To that end, non-ionic surfactants with different molecular weight and structure have been selected (Triton® X-100 and Brij®L23) and compared with organic carbonates (EC:DEC1:1) as plasticizers in lithium polymer electrolytes. The effect of the plasticizer content, salt content and surfactant characteristics on properties such as ionic conductivity, thermal stability and electrochemical stability of lithium polymer electrolytes has been studied. The results obtained show that the non-ionic surfactants studied as plasticizers (Triton® X-100 and Brij®L23) give lithium polymer electrolytes with higher thermal and electrochemical stability than organic carbonates, thus making them promising plasticizers for lithium polymer electrolytes, especially for high voltage lithium-ion batteries. Surfactant structure could influence the ionic conductivity of the polymer electrolytes, with the linear surfactants being more suitable for this application.

Keywords:
polymer electrolyte; surfactant; lithium battery; plasticizer; PVdF-HFP

Issue: 2021 Volume 58, Issue 1

Pages: 237-247

Publication date: 2021/4/5

https://doi.org/10.37358/MP.21.1.5463

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
ZUBIZARRETA, L., GIL-AGUSTI, M., ESPINOSA, J.C., GARCIA-PELLICER, M., QUIJANO-LOPEZ, A., Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers, Mater. Plast., 58(1), 2021, 237-247. https://doi.org/10.37358/MP.21.1.5463

Vancouver
Zubizarreta L, Gil-Agusti M, Espinosa JC, Garcia-Pellicer M, Quijano-Lopez A. Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers. Mater. Plast.[internet]. 2021 Jan;58(1):237-247. Available from: https://doi.org/10.37358/MP.21.1.5463

APA 6th edition
Zubizarreta, L., Gil-Agusti, M., Espinosa, J.C., Garcia-Pellicer, M. & Quijano-Lopez, A. (2021). Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers. Materiale Plastice, 58(1), 237-247. https://doi.org/10.37358/MP.21.1.5463

Harvard
Zubizarreta, L., Gil-Agusti, M., Espinosa, J.C., Garcia-Pellicer, M., Quijano-Lopez, A. (2021). 'Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers', Materiale Plastice, 58(1), pp. 237-247. https://doi.org/10.37358/MP.21.1.5463

IEEE
L. Zubizarreta, M. Gil-Agusti, J.C. Espinosa, M. Garcia-Pellicer, A. Quijano-Lopez, "Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers". Materiale Plastice, vol. 58, no. 1, pp. 237-247, 2021. [online]. https://doi.org/10.37358/MP.21.1.5463

Text
Leire Zubizarreta, Mayte Gil-Agusti, Juan Carlos Espinosa, Marta Garcia-Pellicer, Alfredo Quijano-Lopez,
Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers,
Materiale Plastice,
Volume 58, Issue 1,
2021,
Pages 237-247,
ISSN 2668-8220,
https://doi.org/10.37358/MP.21.1.5463.
(https://revmaterialeplastice.ro/Articles.asp?ID=5463)
Keywords: polymer electrolyte; surfactant; lithium battery; plasticizer; PVdF-HFP

RIS
TY - JOUR
T1 - Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers
A1 - Zubizarreta, Leire
A2 - Gil-Agusti, Mayte
A3 - Espinosa, Juan Carlos
A4 - Garcia-Pellicer, Marta
A5 - Quijano-Lopez, Alfredo
JF - Materiale Plastice
JO - Mater. Plast.
PB - Materiale Plastice SRL
SN - 2668-8220
Y1 - 2021
VL - 58
IS - 1
SP - 237
EP - 247
UR - https://doi.org/10.37358/MP.21.1.5463
KW - polymer electrolyte
KW - surfactant
KW - lithium battery
KW - plasticizer
KW - PVdF-HFP
ER -

BibTex
@article{MatPlast2021P237,
author = {Zubizarreta Leire and Gil-Agusti Mayte and Espinosa Juan Carlos and Garcia-Pellicer Marta and Quijano-Lopez Alfredo},
title = {Studying the Properties of PVdF-HFP Based Lithium Polymer Electrolytes Using non-ionic Surfactants as Plasticizers},
journal = {Materiale Plastice},
volume = {58},
number = {1},
pages = {237-247},
year = {2021},
issn = {2668-8220},
doi = {https://doi.org/10.37358/MP.21.1.5463},
url = {https://revmaterialeplastice.ro/Articles.asp?ID=5463}
}

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