Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties

Huang, Hao; Zhang, Yan-Hua; Zhao, Li-Sha; Luo, Guang-Ming; Cai, Yan-Hua

Hao Huang, Yan-Hua Zhang, Li-Sha Zhao, Guang-Ming Luo, Yan-Hua Cai

Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties

Abstract:
This work was aimed at synthesizing the N, N'-isophthalic bis(piperonylic acid) dihydrazide (PAID) to be as a new crystallization accelerator for poly(L-lactide) (PLLA), and a detailed investigations of the non-isothermal crystallization, melting behavior, thermal decomposition behavior and mechanical properties of PLLA nucleated by PAID were performed applying differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and electronic tensile tester. The melt-crystallization proved that the PAID could act as a heterogeneous nucleating agent to significantly promote the crystallization in cooling, even the crystallization was still able to be accelerated upon the fast cooling at 50 oC/min. The final melt temperature was another crucial factor for PLLA’s melt crystallization, and when the final melt temperature was 170 oC, the onset crystallization temperature and melt-crystallization enthalpy was almost up to 150 oC and 56.8 J/g upon cooling of 1 oC/min, respectively. Furthermore, the chemical nucleation was proposed to be the nucleation mechanism of PAID for PLLA via the preliminary theoretical calculation. For the cold-crystallization, the addition of PAID exhibited an inhibition for the crystallization of PLLA, but the total crystallization process depended on the heating rate and PAID concentration. The single melting peak after cooling of 1 oC/min indicated that the crystallization had been thoroughly completed in cooling. Additionally, the single melting peak with different locations after full crystallization resulted from the different crystallization temperatures. A comparison in the onset decomposition temperature implied that the presence of PAID only slightly decreased the thermal stability of PLLA. The mechanical testing showed that, in contrast with the elongation at break, the existence of PAID enhanced the tensile strength of PLLA.

Keywords:
poly(L-lactide); nucleating agent; crystallization; piperonylic acid; isophthalic dihydrazide

Issue: 2020 Volume 57, Issue 3

Pages: 28-40

Publication date: 2020/9/30

https://doi.org/10.37358/MP.20.3.5377

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
HUANG, H., ZHANG, Y., ZHAO, L., LUO, G., CAI, Y., Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties, Mater. Plast., 57(3), 2020, 28-40. https://doi.org/10.37358/MP.20.3.5377

Vancouver
Huang H, Zhang Y, Zhao L, Luo G, Cai Y. Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties. Mater. Plast.[internet]. 2020 Jul;57(3):28-40. Available from: https://doi.org/10.37358/MP.20.3.5377

APA 6th edition
Huang, H., Zhang, Y., Zhao, L., Luo, G. & Cai, Y. (2020). Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties. Materiale Plastice, 57(3), 28-40. https://doi.org/10.37358/MP.20.3.5377

Harvard
Huang, H., Zhang, Y., Zhao, L., Luo, G., Cai, Y. (2020). 'Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties', Materiale Plastice, 57(3), pp. 28-40. https://doi.org/10.37358/MP.20.3.5377

IEEE
H. Huang, Y. Zhang, L. Zhao, G. Luo, Y. Cai, "Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties". Materiale Plastice, vol. 57, no. 3, pp. 28-40, 2020. [online]. https://doi.org/10.37358/MP.20.3.5377

Text
Hao Huang, Yan-Hua Zhang, Li-Sha Zhao, Guang-Ming Luo, Yan-Hua Cai,
Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties,
Materiale Plastice,
Volume 57, Issue 3,
2020,
Pages 28-40,
ISSN 2668-8220,
https://doi.org/10.37358/MP.20.3.5377.
(https://revmaterialeplastice.ro/Articles.asp?ID=5377)
Keywords: poly(L-lactide); nucleating agent; crystallization; piperonylic acid; isophthalic dihydrazide

RIS
TY - JOUR
T1 - Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties
A1 - Huang, Hao
A2 - Zhang, Yan-Hua
A3 - Zhao, Li-Sha
A4 - Luo, Guang-Ming
A5 - Cai, Yan-Hua
JF - Materiale Plastice
JO - Mater. Plast.
PB - Materiale Plastice SRL
SN - 2668-8220
Y1 - 2020
VL - 57
IS - 3
SP - 28
EP - 40
UR - https://doi.org/10.37358/MP.20.3.5377
KW - poly(L-lactide)
KW - nucleating agent
KW - crystallization
KW - piperonylic acid
KW - isophthalic dihydrazide
ER -

BibTex
@article{MatPlast2020P28,
author = {Huang Hao and Zhang Yan-Hua and Zhao Li-Sha and Luo Guang-Ming and Cai Yan-Hua},
title = {Insight into the Role of a Isophthalic Dihydrazide Derivative Containing Piperonylic Acid in Poly(L-lactide) Nucleation: Thermal Performances and Mechanical Properties},
journal = {Materiale Plastice},
volume = {57},
number = {3},
pages = {28-40},
year = {2020},
issn = {2668-8220},
doi = {https://doi.org/10.37358/MP.20.3.5377},
url = {https://revmaterialeplastice.ro/Articles.asp?ID=5377}
}

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