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Materiale Plastice
Cite as: Mater. Plast.
https://doi.org/10.37358/Mat.Plast.1964

OSIM Nr. R102356
ISSN Print 0025-5289
ISSN Online 2668-8220
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Materiale Plastice (Mater. Plast.), Year 2008, Volume 45, Issue 2,





Synthesis and Characterization of Some Polyazomethine-urethane-urea Metal-Complexes


Abstract:
A new type of polyurethane metal-complex was prepared by incorporating the transition metal ions such as copper (II), cobalt (II) and nickel (II), into polyazomethine-urethane-urea, containing functional groups. Polyazomethine-urethane-urea (PAMU) was synthesized from 5,5’-methylene-bissalicylaldehyde (MBS) by reaction with an urethane prepolymer based on polyethylene adipate diol (PEA), hexamethylene diisocyanate (HDI) and ethylene diamine (EDA), in DMF as solvent, using 0.5 wt % dibutyltindilaurate (DBDTL) as catalyst. The polymeric Schiff base was converted to the chelates of the metal salts. This complex was performed by mixing of the polyazomethine-urethane-urea, containing functional groups, with the metal salts in DMF as solvent. The polyurethane metal-complexes were characterized by FT-IR spectroscopy and elemental analysis. The polymer property investigated was their thermal stability which was studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The aim of this work is to present a general idea of the various methods of preparation, properties, and applications of metal-containing polyurethanes. Keywords: polyazomethine-urethane-urea, chelate polymers, metal-polymer complex



Issue: 2008 Volume 45, Issue 2
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